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Biguanide and its N-substitutes derivatives represent a difunctional compounds group known for their diversity therapeutical activities, such as antimalarial, antibacterial, disinfectant, antiviral, antihyperglycaemic agents and recently literature reports as analgesic and antidepressant drugs, selective agonists? serotoninergics for the serotonin 5-HT3 receptors. In the last years the literature points out a large practical applications spectrum of the 4f metal complexes for their remarcable spectroscopy, optical...