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The mouth areas of the seas are the most interesting and complex objects for studying the distribution of pollutant flows and the factors of their formation. Different approaches can be used to identify pollutant flows and the role of the geochemical barriers, in particular the analysis of the distribution of marker compounds that most clearly reflect the pollution levels themselves and possible sources of their entry into the components of the aquatic systems. Polycyclic aromatic hydrocarbons (PAHs) are considere...