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Geochemical barriers are the special type of natural systems boundaries. They prevent the penetration of some of substances and are open for the migration of others. For the inorganic substances, especially for the metal ions the barriers are studied enough completely: the models of barriers are developed, the penetration and accumulation kinetic is assessed. But for the organic compounds the role of the geochemical barriers is practically not studied. Especially important are such assessments from the point of vi...