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In the conditions of the deterioration of the structure of reserves of conditioned oil, development of non-traditional sources of hydrocarbon raw materials is becoming one of the promising directions of increasing the resource base of hydrocarbons. The work is devoted to the identification of changes in the chemical structure and composition of super-viscous oil as a result of steam-heat treatment in the presence of mineral compounds of carbonate reservoir rocks at temperatures of 250-300°C and pressures up to 1.6...

On the example of 50 heavy oil fields prepared by PJSC «Tatneft» for pilot development in the territory of Tatarstan, the relationships of the changes in their properties: density, sulfur and paraffin content with the oil-bearing area, effective average oil-saturated thickness of reservoir productive rocks, as well as with coefficient of their sand content, permeability and porosity were investigated. The analysis showed differentiation of technological properties of heavy oils within the same productive layers, c...

Presently intensification of heavy oil production, particularly by applying various catalytic systems, is very attractive and relevant task for many researchers. Catalysts intensify a destruction process of high molecular compounds such as resins and asphaltenes. Thus, providing irreversible viscosity reduction of nonconventional crude oils. In this regard, investigation of ultra-dispersed catalysts based on transition metals is of current interest. The small particle sizes of catalysts yield a strong activity dur...

The resins extracted from heavy oil sample from Ashalcha oilfield (Tatarstan, Russia) and the products of Co-based catalytic and non-catalytic aquathermolysis are investigated. Saturates and four subfractions of resins (R1-R4) are extracted by liquid adsorption chromatography method with individual and solvents. Fractionation method leads to obtain more detail information about the structure of high molecular weight compounds due to subdividing large molecule and its aggregates into small ones. The extracted subfr...

Heavy crudes and natural bitumen might present one of the accessible energy resources for the period of time necessary for the adoption of novel energy technologies of the future. Their development is characterized with low profitability, due to peculiarities of composition, mainly high content of high-molecular paraffin, resin and asphaltenes. At the present time in exploration of heavy hydrocarbon resources, thermal methods of production are being given more attention to. One of the key problems of thermal metho...

With the rapid development of Turkey?s petroleum industry, oil production, the way of burning crude oil to produce steam, need to change. Heavy oil reservoir with thin layer or edge water is unsuitable for thermal recovery. Electric heating leads to considerable electrical consumption. Low injection water temperature decreases reservoir temperature and increased crude oil viscosity. The prolonged temperature difference break up reservoir pore throat cement and framework minerals. To improve high-capacity channel c...

Vanadium and nickel are concentrated in the asphaltene-resinous part of the oil; while the maximum amount of these metals is found in asphaltenes. Vanadium as the vanadyl cation VO2+ and nickel in the form of the cation Ni2+ are coordinated predominantly by porphyrins and their tetrapyrrole analogs. Petroleum feedstock with high metals content is unsuitable for catalytic refining processes. In addition, vanadium and nickel significantly affect the thermal cracking and hydrodemetallization of heavy oil residues. Pr...

The effect of coke formation on the pore structure and permeability in the process of the in-situ upgrading of heavy oil under supercritical condition has attracted more and more attention. Studying coke formation induced by thermal treatment is currently an important task for selecting the optimum upgrading technologies for heavy and extra-heavy oils. This research is intended to evaluate coke formation through the process of aquathermolysis in the condition of superheated steam injection. In this study, upgradin...

In recent years the interest in supercritical fluids is growing. The transition of water into the supercritical state occurs in a closed volume when it reaches the temperature of 374°C and the pressure of 21.8 MPa. At that, the boundary between liquid and vapor disappear a new state of water has a low viscosity and a high diffusion capacity. To analyze the bituminous oil in supercritical water with ultra-dispersed magnetite particles andcaustobiolith. Experiments conducted in a closed reactor under conditions that...