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Polysorbates as hydrophilic surface-active structures are food additives with multifunctional competences (emulsifiers, aerating, wetting, foaming, stabilizing agents) and wide HLB range. The present paper has proposed to know the details of the successive transesterification of 2,5 пїЅ diacetyl пїЅ isosorbide (2,5- Ac2ISB) with hydrocarbon chains (Ra) by successive introducing the different amounts of fatty acids obtained from the vegetal lipid fractions isolated from sweet pepper (Capsicum annuum) and chilli pep...