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The Ogosta Valley downstream the town of Chiprovtsi, NW Bulgaria, was subject to long-lasting contamination with arsenic and other toxic elements due to mining and ore-processing activities in the second half of the last century. Although the exploitation of lead-silver and iron ores was ceased in the end of the 90`s, the soil in particular sections of the Ogosta?s river floodplain remained highly contaminated with arsenic, lead and other heavy metals. Arsenic mobilization and transport in the vadose zone is highl...