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Amines are the key intermediates for agricultural, pharmaceutical, textile, polymer industry etc. The common method for the amines production from the fossil resources, in spite of the high yield of the target products, is characterized by the high amount of side toxic products. Nowadays the production of bio-based amines, in particularly the derivatives of sugars, is of the growing interest. This route of amine production results in the minor waste formation and can be considered as a sustainable. Among various r...

Amines play an important role in the modern chemical engineering. It is a key intermediate for agricultural, pharmaceutical, textile, polymer and other fields of industry. Bio-basedamines, e.g. the derivatives of isohexides, are of a great attention. Nowadays, different methods of the synthesis of polyamides, polyimides, polyesters, polyurethanes, and polycarbonates on the base of isohexides are developed. Thus, mono- and diamine derivatives of D-isosorbide are considered to be a prospective feedstock for polyamid...

Pd-catalyzed reactions are one of the most widespread in fine organic synthesis. For example, selective hydrogenation of alkynols is used for production of a large variety of terpenoids and also fat-soluble vitamins. The challenge in hydrogenation of triple carbon-carbon bond using Pd nanoparticles (NPs) is to provide high activity, selectivity and stability of catalytic system. This work is devoted to the investigation of the influence of the type of anion (OH-, CO32-, PO43-), which was introduced in the catalyst...