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Experimental modeling with the aim of elucidation of the geochemical behaviour of heavy metal pollutants (Pb, Zn, Cd, Cu, Ni, Mn, Fe) and As during interphase processes in metallurgy contaminated area are carried out in 3 aspects: I. Water-soil interaction chemical simulation: 3D –lixiviation of soils and acid rain impact modeling, revealing consequences for a secondary remobilization and increasing the environmental risk for groundwater, vegetables, etc. II. Sorption ability of soils with fixing possibilities, ...