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High performance environmentally friendly aqueous adhesive nanodispersions for shoe manufacture were obtained by improving the polychloroprene adherence by chemical grafting of polychloroprene latex DISPERCOLL C 84 with methyl methacrylate in the presence of benzoyl peroxide as initiator. Grafting is demonstrated by the absence of monomer and polmethylmethacrylate in dispersions, decreasing of intensity of some bands assigned to polychloroprene as well as broadening and splitting of its C-C stretching band due to ...