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CATALYTIC HYDROTREATING OF KRAFT LIGNIN TO PRODUCE BIOFUEL COMPONENTS
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V. Matveeva;E. Shimanskaya;M. Sulman;A. Filatova;A. Stepacheva
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1314-2704
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English
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18
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4.1
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This paper presents the results of the study of Kraft lignin hydrogenolysis process, using 5%Pd/C. The catalyst was investigated using the following physico-chemical methods: X-ray photoelectron spectroscopy, infrared spectroscopy of diffuse reflection of the adsorption of CO (DRIEFT), transmission electron microscopy, thermal gravimetric analysis, differential scanning calorimetry, the low-temperature nitrogen adsorption. Among the products obtained during hydrogenolysis of lignin the most promising for fuels are aromatic hydrocarbons (benzene, toluene, cyclohexane), and also phenolic compounds which can be used as additives to conventional fuels and fuels derived from biomass. Furthermore, a number of cyclic and aromatic hydrocarbons, can also be used in various fields of fine chemicals as solvents and reagents. Maximum feedstock conversion was achieved at 300 °C (98%). Maximum selectivity to phenol was achieved at 250 °C (68% selectivity at 90% conversion). The optimal solvent is 2-propanol.
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conference
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18th International Multidisciplinary Scientific GeoConference SGEM 2018
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18th International Multidisciplinary Scientific GeoConference SGEM 2018, 02-08 July, 2018
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Proceedings Paper
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STEF92 Technology
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International Multidisciplinary Scientific GeoConference-SGEM
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Bulgarian Acad Sci; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Russian Acad Sci; Serbian Acad Sci & Arts; Slovak Acad Sci; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; World Acad Sci; European Acad Sci, Arts & Letters; Ac
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179-186
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02-08 July, 2018
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website
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cdrom
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1117
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lignin; hydrogenolysis; phenol; 2-propanol; biomass
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