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Title: THE ROLE OF ALKALI METAL COMPOUNDS IN SYNTHESIS OF EFFECTIVE POLYMER-BASED PALLADIUM CATALYSTS OF SELECTIVE HYDROGENATION
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THE ROLE OF ALKALI METAL COMPOUNDS IN SYNTHESIS OF EFFECTIVE POLYMER-BASED PALLADIUM CATALYSTS OF SELECTIVE HYDROGENATION
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1314-2704
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English
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18
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4.1
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Pd-catalyzed reactions are one of the most widespread in fine organic synthesis. For example, selective hydrogenation of alkynols is used for production of a large variety of terpenoids and also fat-soluble vitamins. The challenge in hydrogenation of triple carbon-carbon bond using Pd nanoparticles (NPs) is to provide high activity, selectivity and stability of catalytic system. This work is devoted to the investigation of the influence of the type of anion (OH-, CO32-, PO43-), which was introduced in the catalyst Pd/HPS (Pd NPs stabilized by hypercrosslinked polystyrene (HPS)) during the post-impregnation procedure. Moreover, the influence of the addition of alkali metal (Na+) at the stage of catalyst synthesis was considered.
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conference
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18th International Multidisciplinary Scientific GeoConference SGEM 2018
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18th International Multidisciplinary Scientific GeoConference SGEM 2018, 02-08 July, 2018
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Proceedings Paper
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STEF92 Technology
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International Multidisciplinary Scientific GeoConference-SGEM
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Bulgarian Acad Sci; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Russian Acad Sci; Serbian Acad Sci & Arts; Slovak Acad Sci; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; World Acad Sci; European Acad Sci, Arts & Letters; Ac
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727-732
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02-08 July, 2018
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website
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cdrom
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1187
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selective hydrogenation; 2-methyl-3-butyn-2-ol; palladium; alkali metals; hypecrosslinked polystyrene
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