Peer-reviewed articles 17,970 +



Title: SYNTHESIS AND CATALYTIC PROPERTIES OF CU-CONTAINING COMPLEX ZR-AL-CE-OXIDES FOR ETHANOL CONVERSION

SYNTHESIS AND CATALYTIC PROPERTIES OF CU-CONTAINING COMPLEX ZR-AL-CE-OXIDES FOR ETHANOL CONVERSION
A. Pylinina;S. Chuklina;S. Maslenkova;L. Podzorova
1314-2704
English
18
6.3
Ethanol dehydrogenation is commonly used as a process of production valuable products: acetaldehyde - the starting material for the synthesis of a large number of industrial chemicals such as acetic acid, acetate esters and hydrogen - attractive product for renewable energy. It is important also that alcohols produced from biomass (bio alcohols) can be considered as a renewable raw material.
The purpose of this study was to elucidate the effect of composition and synthesis method of Al-Zr-Ce-complex oxides with 5%Cu on its catalytic activity in vapor-phase reactions of ethanol.
We investigated the effect of preparation method, phase composition, calcination temperature and Cu-modification of the Zr-Al mixed oxides on their structural features and catalytic performance in bio ethanol conversion. Zirconia?alumina mixed oxides with different atomic ratios were prepared via sol?gel method. Physicochemical properties were determined using XRD, BET and FT-IR-spectroscopy. Catalytic activity and selectivity were investigated for ethanol conversion to acetaldehyde.
conference
18th International Multidisciplinary Scientific GeoConference SGEM 2018
18th International Multidisciplinary Scientific GeoConference SGEM 2018, 02-08 July, 2018
Proceedings Paper
STEF92 Technology
International Multidisciplinary Scientific GeoConference-SGEM
Bulgarian Acad Sci; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Russian Acad Sci; Serbian Acad Sci & Arts; Slovak Acad Sci; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; World Acad Sci; European Acad Sci, Arts & Letters; Ac
349-354
02-08 July, 2018
website
cdrom
1998
mixed oxides; dehydrogenation; ethanol; selectivity