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PRELIMINARY STUDY ON THE ADSORPTION OF PETROLEUM HYDROCARBONS USING NATURAL ZEOLITIC TUFF FROM ROMANIA
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H.Alexandra;E. Kovacs;C. Roman;M. Senila; I.Aschilean
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1314-2704
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English
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20
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6.1
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Various eco-friendly and cost-effective hydrocarbons clean-up methods based on natural sorbents were developed and tested, in order to prevent the massive environmental damage due to the petroleum spills. Among these sorbents, natural zeolitic tuffs are easily available and have numerous adsorptive properties that make them appropriate for the removal of petroleum substances. This study aims to preliminary investigate the sorption capacity of natural zeolites from a deposit located at Racos, Brasov County, Romania for diesel oil sorption. Two different zeolitic materials having particles size <10 microns and 1-3 mm, thermally activated at two different temperatures, were used in this study. Zeolite samples were characterized in terms of major elements and major oxides contents, using inductively coupled plasma optical emission spectrometry (ICP-OES), after acid digestion and also in terms of Cation Exchange Capacity (CEC). For the experiments, an amount of 3.5 g of each adsorbing materials was placed in crystallizing glass columns dish, then diesel oil was added until the saturation of the whole bed. Afterwards, the excess of diesel oil was removed using a filter paper. The sorption capacity (SC) was determined by weighing. The results showed SC ranging between 0.19 ? 0.26 g/g, for zeolites with particles size of 1-3 mm and, much higher SC, in the range of 1.5 ? 1.6 g/g, for zeolites with particles size < 10 microns. This study offers valuable information for the use of Romanian natural zeolites in the clean-up of different media contaminated with petroleum hydrocarbons.
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conference
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20th International Multidisciplinary Scientific GeoConference SGEM 2020
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20th International Multidisciplinary Scientific GeoConference SGEM 2020, 18 - 24 August, 2020
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Proceedings Paper
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STEF92 Technology
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International Multidisciplinary Scientific GeoConference-SGEM
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SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Russian Acad Sci; Serbian Acad Sci & Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts & Letters; Acad Fine Arts Zagreb Croatia; C
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109-116
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18 - 24 August, 2020
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website
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cdrom
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7523
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low-cost adsorbent; natural zeolite; petroleum hydrocarbons sorption; oil spill
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