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Title: CRITICAL ELEMENTS IN SEQUENTIAL LEACHED PHASES FROM DEEP-SEA POLYMETALLIC NODULES AND SEDIMENTS
CRITICAL ELEMENTS IN SEQUENTIAL LEACHED PHASES FROM DEEP-SEA POLYMETALLIC NODULES AND SEDIMENTS

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Atanas Hikov; Zlatka Milakovska; Valentina Lyubomirova; Nadezhda Lihareva
10.5593/sgem2024/1.1/s01.05
10.5593/sgem2024/1.1
1314-2704
978-619-7603-67-5
English
24
1.1
•    Prof. DSc. Oleksandr Trofymchuk, UKRAINE 
•    Prof. Dr. hab. oec. Baiba Rivza, LATVIA
1.Geology
The deep-sea metalliferous sediments and Fe-Mn polymetallic nodules formed in modern environment at the deep-sea ocean floor (> 4000 m depth) were evaluated as promising new raw materials, especially for critical elements as Li, Co, Cu, Mn, Ni, and rare earth elements (REE). We use а selective sequential leaching procedure to study the distribution of main and trace elements in sequential leached phases from deep-sea polymetallic nodules and sediments from the eastern part of the Clarion-Clipperton fractures zone, NE Pacific. Results show extraction of Mn in the leach 2 in both nodules and sediments. Cobalt, Ni, Cu, Zn have similar behavior because these elements are preferentially incorporated into MnO2 phases. The extraction of Fe, K, P and most of trace elements is different for leach 2, 3 and residual fraction for nodules and sediments. Partially extraction of Fe in leach 2 and the extraction of P from sediments in leach 2 attests to the presence of FeOOH and authigenic fine-grained phosphate component (apatite) which are intergrown with the Mn oxyhydroxides. The second group of elements (Al, Fe, Ti, K, Rb, V, Zr, Nb, Mo, Sb, W, Ba, U) represents a detrital (illite, kaolinite, chlorite, andesine, zircon, rutile) and authigenic (barite) composition and has higher content in the residual fraction in sediments. Part of these elements (Zr, Nb, Mo, U) as well as Sc, Y and REE have strong positive correlation with phosphorous and form the third group of elements which is bound in the authigenic apatite. The results will reveal the main factors that control the trace element concentration in both polymetallic nodules and sediments and help future extraction of these raw materials.
[1] Abbott A., Lohr S., Trethewy M., Are clay minerals the primary control on the oceanic Rare Earth Element budget?, Frontiers in Marine Science, vol. 6, 504, pp 83–101, 2019. https://doi.org/10.3389/fmars.2019.00504.
[2] Balaz P., Results of the first phase of the deep-sea polymetallic nodules geological survey in the Interoceanmetal Joint Organization licence area (2001–2016), Mineralia Slovaca, vol. 53, pp 3–36, 2021. Web ISSN 1338-3523, ISSN 0369-2086.
[3] Dubinin A., Geochemistry of Rare Earth Elements in the ocean, Lithology and Мineral Resources, vol. 39, pp 289–307, 2004.; https://doi.org/10.1023/B:LIMI.0000033816.14825.a2.
[4] Halbach P., Scherhag C., Hebisch U., Marchig V., Geochemical and mineralogical control of different genetic types of deep-sea nodules from the Pacific Ocean, Mineralium Deposita, vol. 16, pp 59–84, 1981.
[5] Hein J., Koschinsky A., Kuhn T., Deep-ocean polymetallic nodules as a resource for critical materials, Nature Reviews Earth & Environment, vol. 1, pp 158–169, 2020. https://doi.org/10.1038/s43017-020-0027-0.
[6] Hikov A., Stefanova E., Stoyanova V., Milakovska Z., Abramowski T., Chavdarova S., Stavrev M., Peytcheva I., Genetic types and REE composition of polymetallic nodules from the eastern part of the Clarion–Clipperton Fractures zone, NE Pacific, In: Christie, A. (Ed.), Proceedings of the 16th SGA Biennial Meeting, New Zeeland, 28-31 March 2022, 1, pp 129–132, 2022a.
[7] Hikov A., Milakovska Z., Stoyanova V., Stefanova E., Abramowski T., Chavdarova S., Stavrev M., REE and trace elements distribution in the deep-sea sediments from the Interoceanmetal (IOM) polymetallic nodule exploration area in the Clarion-Clipperton fractures zone, NE Pacific, Comptes rendus de l’Academie bulgare des Sciences, vol. 75/ issue 7, pp 1018–1027, 2022b.; https://doi.org/10.7546/CRABS.2022.07.10.
[8] Koschinsky A., Halbach P., Sequential leaching of marine ferromanganese precipitates: Genetic implications, Geochimica et Cosmochimica Acta, vol.59/ issue 24, pp 5113–5132, 1995.; https://doi.org/10.1016/0016-7037(95)00358-4.
[9] Kotlinski R., Stoyanova V., Nodule coverage, morphology and distribution in the Eastern CCZ, In: ISA, Technical Study No 6: Prospector’s Guide for Polymetallic Nodule Deposits in the Clarion-Clipperton Fracture Zone, pp 34–42, 2012.
[10] Li Y.H., Schoonmaker J. E., Chemical composition and mineralogy of marine sediments, Treatise on Geochemistry 2nd Edition, vol. 9, pp 1–35, 2014.; http://dx.doi.org/10.1016/B978-0-08-095975-7.00701-4.
[11] Lyubomirova V., Mihaylova V., Djingova R., Chemical characterization of Bulgarian bottled mineral waters, Journal of Food Composition and Analysis, vol. 93, 103595, pp 1–12, 2020.; https://doi.org/10.1016/j.jfca.2020.103595.
[12] Menendez A., James R., Lichtschlag A., Connelly D., Peel K., Controls on the chemical composition of ferromanganese nodules in the Clarion-Clipperton Fracture Zone, eastern equatorial Pacific, Marine Geology, vol. 409, pp 1–14, 2019.; https://doi.org/10.1016/j.margeo.2018.12.004.
[13] Ren J., Liu Y., Wang F., He G., Deng X., Wei Z., Yao H., Mechanism and influencing factors of REY enrichment in deep-sea sediments, Minerals, vol. 11, 196, pp 1–16, 2021.; https://doi.org/10.3390/min11020196.
[14] Stoyanova V., Hikov A., Stefanova E., Milakovska Z., Abramowski T., Peytcheva I., Chavdarova S., Stavrev M., Deep-sea polymetallic nodules as opportunity for future supply with critical raw materials, Review of Bulgarian Geological Society, vol. 82/issue 3, pp 153–155, 2021.; https://doi.org/10.52215/rev.bgs.2021.82.3.153.
[15] Zawadzki D., Maciag J., Abramowski T., McCartney K., Fractionation Trends and Variability of Rare Earth Elements and Selected Critical Metals in Pelagic Sediment from Abyssal Basin of NE Pacific (Clarion-Clipperton Fracture Zone), Minerals, vol. 10, 320, pp 1–38, 2020.; https://doi.org/10.3390/min10040320.
The study was supported by Bulgarian National Science Fund grant KP-06-N34/6.
conference
https://doi.org/10.5593/sgem2024/1.1/s01.05
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Proceedings of 24th International Multidisciplinary Scientific GeoConference SGEM 2024
24th International Multidisciplinary Scientific GeoConference SGEM 2024, 1 - 7 July, 2024
Proceedings Paper
STEF92 Technology
International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM
SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Russian Acad Sci; Serbian Acad Sci and Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts and Letters; Acad Fine Arts Zagreb Croatia; Croatian Acad Sci and Arts; Acad Sci Moldova; Montenegrin Acad Sci and Arts; Georgian Acad Sci; Acad Fine Arts and Design Bratislava; Russian Acad Arts; Turkish Acad Sci.
37-44
1 - 7 July, 2024
website
9837
sequential leaching, critical elements, polymetallic nodules, deep-sea sediments

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