Peer-reviewed articles 17,970 +



Title: VALORIZATION OF WASTE ALKALIS AS REPLACEMENT OF COMMERCIAL ALKALINE ACTIVATOR SOLUTION

VALORIZATION OF WASTE ALKALIS AS REPLACEMENT OF COMMERCIAL ALKALINE ACTIVATOR SOLUTION
Martin Mildner; Jan Fort
10.5593/sgem2022/6.1
1314-2704
English
22
6.1
•    Prof. DSc. Oleksandr Trofymchuk, UKRAINE 
•    Prof. Dr. hab. oec. Baiba Rivza, LATVIA
Current challenges in the building industry are related mostly to the preservation of virgin/natural materials, decreasing the environmental footprint, and increasing the reuse rate of disposed materials. This paper reflects current trends in the use of secondary raw materials of various industrial processes as sources for the production of alternative materials, for example, alkali-activated materials (AAM). Specifically, the paper deals with the description of the basic physical and mechanical properties of finely ground granulated blast furnace slag activated by waste alkali from cleaning processes in the glass industry. To provide more detailed insight into the material microstructure, scanning electron microscopy is employed. Obtained results refer to the capability to produce a material with a compressive strength of 21.7 MPa, which is less of a burden on the environment due to the use of by-products from industrial production. The introduced research line has great potential considering substantial benefits accompanied not only with the replacement of commercial alkali activator solution but also to decrease environmental and financial consequences of demanding waste alkalis disposal.
[1] Costa, F.N., Ribeiro, D.V., Reduction in CO2 emissions during production of cement, with partial replacement of traditional raw materials by civil construction waste (CCW). Journal of Cleaner Production, 276, 2020.
[2] Ali, M.B., Saidur, R., Hossain, M.S. A review on emission analysis in cement industries. Renewable & Sustainable Energy Reviews, vol. 15(5), pp 2252-2261, 2011.
[3] Torres-Carrasco, M. Puertas, F. Alkaline Activation Of Aluminosilicates As An Alternative To Portland Cement: A Review. Revista Romana De Materiale-Romanian Journal of Materials, vol. 47(1), pp. 3-15, 2017.
[4] Torres-Carrasco, M., Puertas, F. Alkaline activation of different aluminosilicates as an alternative to Portland cement: alkali activated cements or geopolymers. Revista Ingenieria De Construccion, vol. 32(2), pp. 5-12, 2017.
[5] Fort, J., Mildner, M., Keppert, M., Cerny, R. Waste solidified alkalis as activator of aluminosilicate precursors: Functional and environmental evaluation. Journal of Building Engineering, vol. 54, 104598, 2022.
[6] Mikhailova, O., del Campo, A., Rovnanik, P., Fernandez, J.F., Torres-Carrasco, M. In situ characterization of main reaction products in alkali-activated slag materials by Confocal Raman Microscopy. Cement & Concrete Composites, vol. 99, pp. 32-39, 2019.
[7] Fiala, L., Pommer, V., Bohm, M., Scheinherrova, L., Cerny, R. Self-heating alkali activated materials: Microstructure and its effect on electrical, thermal and mechanical properties. Construction and Building Materials, vol. 335, p. 127527, 2022.
[8] Provis, J.L., Palomo, A., Shi, C.J. Advances in understanding alkali-activated materials. Cement and Concrete Research, vol. 78, pp. 110-125, 2015.
[9] Abdulkareem, M., Havukainen, J., Nuortila-Jokinen, J., Horttanainen, M. Environmental and economic perspective of waste-derived activators on alkali-activated mortars. Journal of Cleaner Production, vol. 280, p. 124651, 2021.
[10] Nadoushan, M.J., Ramezanianpour, A.A. The effect of type and concentration of activators on flowability and compressive strength of natural pozzolan and slag-based geopolymers. Construction and Building Materials, vol. 111, pp. 337-347, 2016.
[11] Wang, S.D., Scrivener, K.L., Pratt, P.L. Factors Affecting The Strength Of AlkaliActivated Slag. Cement and Concrete Research, vol. 24(6), pp. 1033-1043, 1994.
[12] Fu, B., Cheng, Z., Han, J., Li, N. Understanding the Role of Metakaolin towards Mitigating the Shrinkage Behavior of Alkali-Activated Slag. Materials, vol. 14(22), 2021.
This research has been supported by the Czech Science Foundation, under project No 22-04726S.
conference
Proceedings of 22nd International Multidisciplinary Scientific GeoConference SGEM 2022
22nd International Multidisciplinary Scientific GeoConference SGEM 2022, 04 - 10 July, 2022
Proceedings Paper
STEF92 Technology
International Multidisciplinary Scientific GeoConference SGEM
SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Serbian Acad Sci and Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts and Letters; Acad Fine Arts Zagreb Croatia; Croatian Acad Sci and Arts; Acad Sci Moldova; Montenegrin Acad Sci and Arts; Georgian Acad Sci; Acad Fine Arts and Design Bratislava; Turkish Acad Sci.
217-222
04 - 10 July, 2022
website
8655
alkali-activation, blast furnace slag, waste alkalis, replacement, environmental benefit