Peer-reviewed articles 17,970 +



Title: ANALYSIS OF PESTICIDE AND HEAVY METAL RESIDUES IN HONEY BY GC/ECD AND GF-AAS: COMPARISON OF DIFFERENT PRODUCTION AREAS FROM ROMANIA

ANALYSIS OF PESTICIDE AND HEAVY METAL RESIDUES IN HONEY BY GC/ECD AND GF-AAS: COMPARISON OF DIFFERENT PRODUCTION AREAS FROM ROMANIA
Ramona Cristea; Claudia Sandru; Diana Ionela Popescu
10.5593/sgem2022/5.1
1314-2704
English
22
5.1
•    Prof. DSc. Oleksandr Trofymchuk, UKRAINE 
•    Prof. Dr. hab. oec. Baiba Rivza, LATVIA
Residues of pesticides and HM, used in bees care or in crop fields, have negative effects on the health of bees and humans and of the antimicrobial properties of the honey. Investigation of HM and pesticides is vital, since the use of chemical solutions has “rise up” significantly. Our aim was to investigate whether the level of contaminants in honey (Fe, Zn, Pb, Cu, Cd, As, using GC/ECD and GF-AAS) and pesticides: ?-HCH, ?-HCH, ? -HCH, aldrin, dieldrin, endrin, DDE, DDD, and DDT, alpha -Endosulfan, carbofuran, pirimicarb (by gas chromatography with electron capture determination). Iron (max. 0.76725 mg / kg), Zinc, Lead Copper Cadmium, Arsenic have lower values than the maximum allowed; 0.01 mg/ kg is the maximum allowed for pesticides; exception is max. 0.05 mg / kg for DDD, DDT, DDE, Carbofuran and Pirimicarb. The average of the resulting values exceeds the maximum allowed in many cases to four decimal places, as follows: Alpha HCH (max. 0.0158mg / kg), Beta HCH and HCH (by 10-15%), Aldrin (double), alpha endo-sulfan (three times than maximum). Endrin was not detected in any honey samples. Organochlorines in the pp DDE range were below the maximum (0.05 mg / kg). The pyrimicarbon showed lower values. The values determined are not dangerous for the human.
[1] Basson N.J., Grobler S.R., Antimicrobial activity of two South African honeys produced from indigenous Leucospermum cordifolium and Erica species on selected micro-organisms. BMC Complement Altern Med, South Africa, vol.8/issue 41, 2008.
[2] Bogdanov S., Tomislav J., Robert S., Peter G., Honey for nutrition and health: a review, J Am Coll Nutr., vol. 27/issue 6, pp 677-89, 2008.
[3] Calatayud-Vernich P., Calatayud F., Simo E., Suarez-Varela M.M., Pico Y., Influence of pesticide use in fruit orchards during blooming on honeybee mortality in 4 experimental apiaries, Sci Total Environ., vol. 541, pp 33-41, 2016.
[4] Cesnik Helena B., .Kmecl V., Spela Velikonja B., Pesticide and veterinary drug residues in honey - validation of methods and a survey of organic and conventional honeys from Slovenia, Food Addit Contam Part A Chem Anal Control Expo Risk Assess, vol.36/issue 9, pp 1358-1375, 2019.
[5] Chauhan A., Pandey V., Chacko K.M., Khandal R.K., Antibacterial activity of raw and processed honey, Electronic J Biol 2010; 5: 58-66.
[6] Commission Regulation, (EU) 2015/1005 of 25 June 2015 amending Regulation (EC) No 1881/2006 as regards maximum levels of lead in certain foodstuffs. https://eurlex.europa.eu/eli/reg/2015/1005/oj.
[7] Daniel R., Britta P., Guido S., Wolfgang B., Large-scale monitoring of effects of clothianidin-dressed oilseed rape seeds on pollinating insects in northern Germany: residues of clothianidin in pollen, nectar and honey, Ecotoxicology vol. 25, pp1691– 1701, 2016.
[8] EN15662:2008, Foods of plant origin – Determination of pesticide residues using GC/MS and/or LC-MS/MS following acetonitrile extraction/partitioning and clean-up by dispersive SPE – QuEChERS-Method. German version, 2009.
[9] Lambert O., Veyrand B., Durand S., Marchand P., le Bizec B., Piroux M., Puyo S., Thorin C., Delbac F., Pouliquen H., Polycyclic aromatic hydrocarbons: Bees, honey and pollen as sentinels for environmental chemical contaminants. Chemosphere, vol. 86, pp 98–104. doi: 10.1016/j.chemosphere.2011.09.025, 2012.
[10] Lazarus M., Lovakovi B.T., Orct T., Sekovani A., Nina B., Majaoki, Boica Solomun K., Ivana V., Andreja J., Marija Deni L., Dragan B., Difference in pesticides, trace metal(loid)s and drug residues between certified organic and conventional honeys from Croatia, Chemosphere, vol. 266, doi: 10.1016/j.chemosphere.2020.128954. Epub 2020.
[11] Lengyel E., Panaitescu M., Chemical compounds from thymus vulgaris and their antimicrobial activity, Management of Sustainable Development Sibiu, Romania, Vol. 11/issue 1, pp 25-28, Romania, 2019
[12] Klein A.M., Vaissiere B.E., Cane J.H., Steffan-Dewenter I., Cunningham S.A., Kremen C., Tscharntke T., Importance of pollinators in changing landscapes for world crops. Proc Biol Sci, Vol. 74, pp 303–313, 2007.
[13] Nasir N.M., Halim A.S., Singh K.B., Dorai A.A., Haneef M.M., Antibacterial properties of tualang honey and its effect in burn wound management: a comparative study. BMC Complement Altern Med vol.10/issue 31, 2010.
[14] Potts S.G., Biesmeijer J.C., Kremen C., Neumann P., Schweiger O., Kunin W.E., Global pollinator declines: trends, impacts and drivers. Trends Ecol Evol vol. 25, pp 345–353, 2010.
[15] Regulation 396/2005, 2005. Regulation (EC) No 396/2005 of the European Parliament and of the Council of 23 February 2005 on maximum residue levels of pesticides in or on food and feed of plant and animal origin and amending Council Directive 91/414/EEC (text with EEA relevance). https://eur-lex.europa.eu/legalcontent/EN/TXT/?qid?1580730711156&uri?CELEX:32005R0396
conference
Proceedings of 22nd International Multidisciplinary Scientific GeoConference SGEM 2022
22nd International Multidisciplinary Scientific GeoConference SGEM 2022, 04 - 10 July, 2022
Proceedings Paper
STEF92 Technology
International Multidisciplinary Scientific GeoConference SGEM
SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Serbian Acad Sci and Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts and Letters; Acad Fine Arts Zagreb Croatia; Croatian Acad Sci and Arts; Acad Sci Moldova; Montenegrin Acad Sci and Arts; Georgian Acad Sci; Acad Fine Arts and Design Bratislava; Turkish Acad Sci.
19-26
04 - 10 July, 2022
website
8667
Pesticide, heavy metal residues, honey, GC/ECD, GF-AA