Peer-reviewed articles 17,970 +


Title: ADSORPTIVE REMOVAL OF GLYPHOSATE FROM AQUEOUS SOLUTION ONTO PYROPHYLLITE
ADSORPTIVE REMOVAL OF GLYPHOSATE FROM AQUEOUS SOLUTION ONTO PYROPHYLLITE

PlumX Article Metrics by Elsevier
Lejla Klepo; Jelena Ostojic; Olga Borota; Sabina Zero; Dusan Culum
10.5593/sgem2022V/4.2/s18.02
10.5593/sgem2022V/4.2
1314-2704
978-619-7603-50-7
English
22
4.2
•    Prof. DSc. Oleksandr Trofymchuk, UKRAINE 
•    Prof. Dr. hab. oec. Baiba Rivza, LATVIA
Recycling
Pyrophyllite was investigated in this study as a potential adsorbent for the removal of glyphosate, a common herbicide for the control of a wide variety of weeds. There are several publications in the literature that discuss how glyphosate interacts with clay minerals such as montmorillonite, kaolinite, and bentonite, but there is no information regarding the possibility of glyphosate removal from aqueous solution using pyrophyllite. In this study, the adsorption of glyphosate from water samples onto pyrophyllite, a mineral clay from the Parsovici, Konjic mine, was investigated. The ninhydrin reaction was used to spectrophotometrically quantify glyphosate. At 570 nm, the purple Ruhemman product's absorbance was determined. Adsorption capacity (qe), removal efficiency (R), and the partition coefficient are used to express the results (Kd). The outcomes demonstrated that distinct ionic species of glyphosate at different pHs cause the adsorption of glyphosate on pyrophyllite to be pH-dependent. The findings demonstrated that during different contact times, the basic medium can remove up to 75% of glyphosate. According to results from fitting isotherm models, the Freundlich model is slightly better fitted. According to the results of kinetic investigations, the pseudo-2nd order model is more suitable for this kind of adsorption.
[1] Sheals, J., Sjoberg, S., & Persson, P. (2002). Adsorption of Glyphosate on Goethite: Molecular Characterization of Surface Complexes. Environmental Science & Technology, 36(14), 3090–3095. doi:10.1021/es010295w
[2] Bhaskara, B. L., & Nagaraja, P. (2006). Direct Sensitive Spectrophotometric Determination of Glyphosate by Using Ninhydrin as a Chromogenic Reagent in Formulations and Environmental Water Samples. Helvetica Chimica Acta, 89(11), 2686– 2693. doi:10.1002/hlca.200690240
[3] Morillo, E., Undabeytia, T., Maqueda, C., & Ramos, A. (2000). Glyphosate adsorption on soils of different characteristics. Chemosphere, 40(1), 103–107. doi:10.1016/s0045- 6535(99)00255-6
[4] Ren, Z., Dong, Y., & Liu, Y. (2014). Enhanced Glyphosate Removal by Montmorillonite in the Presence of Fe(III). Industrial & Engineering Chemistry Research, 53(37), 14485–14492. doi:10.1021/ie502773j
[5] Pereira, R. C., da Costa, A. C. S., Ivashita, F. F., Paesano, A., & Zaia, D. A. M. (2020). Interaction between glyphosate and montmorillonite in the presence of artificial seawater. Heliyon, 6(3), e03532. doi:10.1016/j.heliyon.2020.e03532
[6] Dixon, J. B., & Schulze, D. G. (2002). An Introduction to Soil Mineralogy. SSSA Book Series. doi:10.2136/sssabookser7.c1
[7] Miyah, Y., Lahrichi, A., Idrissi, M., Boujraf, S., Taouda, H.,, Zerrouq, F. (2016) Assessment of adsorption kinetics for removal potential of Crystal Violet dye from aqueous solutions using Moroccan pyrophyllite. Journal of the Association of Arab Universities for Basic and Applied Sciences, 23, 20-28, DOI: 10.1016/j.jaubas.2016.06.001
[8] Saxena, S., Prasad, M., Amritphale, S. S., and Chandra, N. (2001). Adsorption of cyanide from aqueous solutions at pyrophyllite surface. Separation and Purification Technology, 24(1–2), 263–270. https://doi.org/10.1016/S1383-5866(01)00131-9
[9] Bhatt, A. S., Sakaria, P. L., Vasudevan, M., Pawar, R. R., Sudheesh, N., Bajaj, H. C., & Mody, H. M. (2012). Adsorption of an anionic dye from aqueous medium by organoclays: equilibrium modeling, kinetic and thermodynamic exploration. RSC Advances, 2(23), 8663. doi:10.1039/c2ra20347b
[10] Pavan, F. A., Lima, E. C., Dias, S. L. P., & Mazzocato, A. C. (2008). Methylene blue biosorption from aqueous solutions by yellow passion fruit waste. Journal of Hazardous Materials, 150(3), 703–712. doi:10.1016/j.jhazmat.2007.05.023
[11] Ayub, A., Raza, Z. A., Majeed, M. I., Tariq, M. R., & Irfan, A. (2020). Development of sustainable magnetic chitosan biosorbent beads for kinetic remediation of arsenic contaminated water. International Journal of Biological Macromolecules. doi:10.1016/j.ijbiomac.2020.06.287
[12] Ntim, S.A, & Mitra, S. (2011). Removal of Trace Arsenic To Meet Drinking Water Standards Using Iron Oxide Coated Multiwall Carbon Nanotubes. Journal of Chemical & Engineering Data, 56(5), 2077–2083. doi:10.1021/je1010664
[13] Nourouzi, M., Chuah, T. G., & Choong, T. S. Y. (2010). Adsorption of glyphosate onto activated carbon derived from waste newspaper. Desalination and Water Treatment, 24(1-3), 321–326. doi:10.5004/dwt.2010.1461
[14] Zhou, C., Jia, D., Liu, M., Liu, X., & Li, C. (2017). Removal of Glyphosate from Aqueous Solution Using Nanosized Copper Hydroxide Modified Resin: Equilibrium Isotherms and Kinetics. Journal of Chemical & Engineering Data, 62(10), 3585–3592. doi:10.1021/acs.jced.7b00569
[15] Liu, B., Dong, L., Yu, Q., Li, X., Wu, F., Tan, Z., & Luo, S. (2016). Thermodynamic Study on the Protonation Reactions of Glyphosate in Aqueous Solution: Potentiometry, Calorimetry and NMR spectroscopy. The Journal of Physical Chemistry B, 120(9), 2132– 2137. doi:10.1021/acs.jpcb.5b11550
This study was supported by the Ministry for Education, Science and Youth Grant No 27- 02-11-41250-6/21, Canton Sarajevo, Bosnia and Herzegovina.
This study was also supported by AD Harbi d.o.o. Sarajevo by donating pyrophyllite for this research.
conference
https://doi.org/10.5593/sgem2022V/4.2/s18.02
Download PDF
Proceedings of 22nd International Multidisciplinary Scientific GeoConference SGEM 2022
22nd International Multidisciplinary Scientific GeoConference SGEM 2022, 06-08 December, 2022
Proceedings Paper
STEF92 Technology
International Multidisciplinary Scientific GeoConference SGEM
SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Serbian Acad Sci and Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts and Letters; Acad Fine Arts Zagreb Croatia; Croatian Acad Sci and Arts; Acad Sci Moldova; Montenegrin Acad Sci and Arts; Georgian Acad Sci; Acad Fine Arts and Design Bratislava; Turkish Acad Sci.
13-24
06-08 December, 2022
website
8819
glyphosate, adsorptionm, pyrophyllite