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Title: COMPARATIVE STUDY OF EXTRACTION METHODS FOR THE DETERMINATION OF PAHS IN SOILS USING GC-MS
COMPARATIVE STUDY OF EXTRACTION METHODS FOR THE DETERMINATION OF PAHS IN SOILS USING GC-MS

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A. Kamalova; P. Galitskaya; A. Gordeev; A. Khamieva; P. Kuryntseva
10.5593/sgem2023/5.1/s20.11
10.5593/sgem2023/5.1
1314-2704
978-619-7603-60-6
English
23
5.1
•    Prof. DSc. Oleksandr Trofymchuk, UKRAINE 
•    Prof. Dr. hab. oec. Baiba Rivza, LATVIA
Ecology and Environmental Protection
Soil contamination by polycyclic aromatic hydrocarbons (PAHs) is a widespread concern due to the high potential for human exposure through inhalation, ingestion, and dermal contact. In this study, we compared the efficiency of three different methods for PAHs extraction from model samples, including ultrasonic (US), mechanical shaking and purification with commercial QuEChERS kit (Shq), and ultrasonic extraction coupled with QuEChERS (USq) by gas chromatography coupled to a triple quadrupole tandem mass-spectrometry (GC-MS).
The results showed that in the ultrasonic extraction with subsequent purification using QuEChERS, the content of PAHs in the sample varied from 86.91 to 2211.60 ng/g. Whereas, in mechanical shaking method, this range was in the range 1.56-761.20 ng/g. In the case of ultrasonic extraction without sorbent purification, only for acenaphthene, fluorene, and benzo(g,h,i)perylene, the values were higher compared to the other two methods: 285.78±27.56 ng/g, 577.48±73.62 ng/g, and 266.35±177.30 ng/g, respectively. The comparison of PAH extraction efficiency showed that the combination of ultrasonic extraction and purification with QuEChERS (USq) was the most efficient method and rapid, obtaining the highest yields for all tested PAHs.
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The work is carried out in accordance with the Strategic Academic Leadership Program «Priority 2030» of the Kazan Federal University of the Government of the Russian Federation.
conference
https://doi.org/10.5593/sgem2023/5.1/s20.11
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Proceedings of 23rd International Multidisciplinary Scientific GeoConference SGEM 2023
23rd International Multidisciplinary Scientific GeoConference SGEM 2023, 03 - 09 July, 2023
Proceedings Paper
STEF92 Technology
International Multidisciplinary Scientific GeoConference SGEM
SWS Scholarly Society; Acad Sci Czech Republ; Latvian Acad Sci; Polish Acad Sci; Serbian Acad Sci and Arts; Natl Acad Sci Ukraine; Natl Acad Sci Armenia; Sci Council Japan; European Acad Sci, Arts and Letters; Acad Fine Arts Zagreb Croatia; Croatian Acad Sci and Arts; Acad Sci Moldova; Montenegrin Acad Sci and Arts; Georgian Acad Sci; Acad Fine Arts and Design Bratislava; Turkish Acad Sci.
89-96
03 - 09 July, 2023
website
9279
urban soil, polycyclic aromatic hydrocarbons (PAHs), gas chromatography with mass-selective detector (GC-MS), extraction, QuEChERS