SWS Academic Research eLibraryEarth & Planetary Sciences

Scholarly record

KINETIC STUDY OF CEMENT-ASBESTOS THERMAL DECOMPOSITION PROCESS UNDER ISOTHERMAL CONDITIONS

Robert Kusiorowski, Anna Gerle, Magdalena Kujawa

First published: 2024-12-15https://doi.org/10.5593/sgem2024v/4.2/s17.16View metrics

Abstract

Asbestos is a general name applied to a group of silicate minerals which naturally occur in fibrous form. It is a natural mineral widely used in the past, especially in the construction industry. Despite its good performance properties, it is currently known that asbestos has carcinogenic properties. The problem of storing asbestos wastes is significant worldwide. This especially applies to countries where the production and use of asbestos products is prohibited by law. One of the possible methods of proceeding and solving the above problem is a thermal treatment, which results in thermal decomposition of dangerous asbestos fibers. The kinetic study of the thermal decomposition process carried out for cement-asbestos has been investigated by ex-situ thermal treatment. Obtained results allow for kinetic interpretation of this thermal transformation. The kinetic analysis of the isothermal data using an Avrami model yields values for the overall reaction order. The apparent activation energy of the thermal decomposition process for tested cement-asbestos sample is about 160 kJ/mol.

Publication Impact Profile

PlumX
  • Captures
  • Mendeley - Readers: 1
Dimensions ID: pub.1186962928

Publication details

Title
KINETIC STUDY OF CEMENT-ASBESTOS THERMAL DECOMPOSITION PROCESS UNDER ISOTHERMAL CONDITIONS
Authors
Robert Kusiorowski, Anna Gerle, Magdalena Kujawa
Proceedings
24th International Multidisciplinary Scientific GeoConference Proceedings SGEM 2024, Energy and Clean Technologies, Vol 24, Issue 4.2
Publisher
STEF92 Technology
Year
2024
Pages
109-116
SWS Citekey
Kusiorowski202419109116
ISSN
1314-2704; 13142704
ISBN
9786197603774
Language
en
Publication type
Conference Paper
Proceedings contents
Open official contents
Keywords
References14
  1. Gualtieri A.F., Mineral fibers: crystal chemistry, chemical-physical properties, biological interaction and toxicity, European Mineralogical Union, Great Britain, 2017. doi.org/DOI: 10.1180/EMU-notes.18

  2. Gualtieri A.F., Recycling asbestos-containing material (ACM) from construction and demolition waste (CDW), Handbook of recycled concrete and demolition waste, Woodhead Publishing, Great Britain, 2013. pp 500�525. doi.org/DOI: 10.1533/9780857096906.4.500

  3. Kusiorowski R., Lipowska B., Kujawa M., Gerle A., Problem of asbestos-containing wastes in Poland, Clean Waste System, 2023, 4, 1000085. doi.org/DOI: 10.1016/j.clwas.2023.1000085 https://doi.org/10.1016/j.clwas.2023.100085

  4. Musk A.W., de Klerk N., Reid A., Hui J., Franklin P., Brims F., Asbestos-related diseases, International Journal of Tuberculosis and Lung Disease, 2020, 24(6), 562�567. doi.org/DOI: 10.5588/ijtld.19.0645

  5. Paglietti F., Malinconico S., della Stafa B.C., Bellagamba S., De Simone P., Classification and management of asbestos-containing waste: European legislation and the Italian experience, Waste Management, 2016, 50, 130�150. doi.org/DOI: 10.1016/j.wasman.2016.02.014

  6. Li J., Dong Q., Yu K., Liu L., Asbestos and asbestos waste management in the Asian-Pacific region: trends, challenges and solutions, Journal of Cleaner Production, 2014, 81, 218�226. doi.org/DOI: 10.1016/j.jclepro.2014.06.022

  7. Szymanska D., Lewandowska A., Disposal of asbestos and products containing asbestos in Poland, Journal of Materials Cycles and Waste Management, 2019, 21, 345�355. doi.org/DOI: 10.1007/s10163-018-0796-4

  8. Spasiano D., Pirozzi F., Treatments of asbestos containing wastes, Journal of Environmental Management, 2017, 204, 82�91. doi.org/DOI: 10.1016/j.jenvman.2017.08.038

  9. Paolini V., Tomassetti L., Segreto M., Borin D., Liotta F., Torre M., Petracchini F., Asbestos treatment technologies. Journal of Materials Cycles and Waste Management, 2019, 21, 205�226. doi.org/10.1007/ s10163-018-0793-7 DOI: 10.1007/s10163-018-0793-7

  10. Gualtieri A.F., Giacobbe C., Sardisco L., Saraceno M., Gualtieri M.L., Lusvardi G., Cavenati C., Zanatto I., Recycling of the product of thermal inertization of cement�asbestos for various industrial applications. Waste Management, 2011, 31, 91�100. doi.org/DOI: 10.1016/j.wasman.2010.07.006

  11. Zaremba T., Krzakala A., Piotrowski J., Garczorz D., Study on the thermal decomposition of chrysotile asbestos, Journal of Thermal Analysis and Calorimetry, 2010, 101, 479�485. doi.org/DOI: 10.1007/s10973-010-0819-4

  12. Kusiorowski R., Zaremba T., Piotrowski J., Gerle A., Thermal decomposition of asbestos-containing materials. Journal of Thermal Analysis and Calorimetry, 2013, 113, 179�188. doi.org/DOI: 10.1007/s10973-013-3038-y

  13. Viani A., Gualtieri A.F., Pollastri S., Rinaudo C., Croce A., Urso G., Crystal chemistry of the high temperature product of transformation of cement-asbestos, Journal of Hazardous Materials, 2013, 248�249, 69�80. doi.org/DOI: 10.1016/j.jhazmat.2012.12.030

  14. Kusiorowski R., Gerle A., Kujawa M., Sliwa A., Adamek J., Charaterisation of asbestos-containing wastes by thermal analysis, Journal of Thermal Analysis and Calorimetry, 2024. doi.org/DOI: 10.1007/s10973-024-13312-3

View or Download full articleAccess options
Full paper accessChoose SWS login, librarian support, or instant article download.

SWS access login

Login as SWS Scientific Committee

Authors and approved SWS contributors will read and export their own linked papers after identity matching by SWS profile, email and SGEM GlobalID.

For librarian assistance: [email protected]

Purchase Instant Access

48-hour online accessComing soon
Online-only accessComing soon
Download the full article in PDF formatEUR 35
  • Article can be downloaded after successful payment.
  • Article may be used according to SWS library access terms.
  • Article cannot be redistributed.
Get full paper

Back to publication list