MODELING THE SYNTHESIS OF AN OXYGENATED BIOFUEL ADDITIVE

Agirre I., Garcı´a I., Requies J., Barrio V.L., Güemez M.B., Cambra J.F., Arias P.L., Glycerol acetals, kinetic study of the reaction between glycerol and formaldehyde , Biomass and bioenergy, Spain, vol. 35, pp. 3636-3642, 2011.

De Torres M., Gonzalo J. , Mayoral J. A., Pires E., Santos M., Glycerol ketals: Synthesis and profits in biodiesel blends, Fuel, Spain, vol. 94, pp. 614–616, 2012. International Multidisciplinary Scientific GeoConfenferences SGEM 2015 www.sgem.org 15th International Multidisciplinary Scientific GeoConferences SGEM2015

Esteban J. , Ladero M. , García -Ochoa F., Kinetic modelling of the solventless synthesis of solketal with a sulphonic ion exchange resin, Chemical Engineering Journal, Spain, vol. 269, pp. 194–202, 2015.

Oprescu E. -E., Dragomir R.-E., Radu E., Radu A., Velea S., Bolocan I., Stepan E., Rosca P., Performance and emission characteristics of diesel engine powered with diesel– glycerol derivatives blends, Fuel Processing Technology, Romania, vol. 126, pp. 460-468, 2014.

Hong X., McGiveron O., Kolah A.K., Orjuela A., Peereboom L., Lira C.T., Miller D.J., Reaction kinetics of glycerol acetal formation via transacetalization with 1,1- diethoxyethane, Chemical Engineering Journal, vol. 222, pp. 374–381, 2013.

Capeletti M.R., Balzano L., de la Puente G., Laborde M., Sedran U., Synthesis of acetal (1,1-diethoxyethane) from ethanol and acetaldehyde over acidic catalysts, Applied Catalysis A: General, vol. 198, pp. L1-L4 , 2000.

Agirre I., Güemez M.B., Ugarte A., Requies J., Barrio V.L., Cambra J.F., Arias P.L., Glycerol acetals as diesel additives: Kinetic study of the reaction between glycerol and acetaldehyde, Fuel Processing Technology, vol. 116, pp. 182–188, 2013.

Reddy P. S., Sudarsanam P. , Mallesham B. , Raju G. , Reddy B. M., Acetalisation of glycerol with acetone over zirconia and promoted zirconia catalysts under mild reaction conditions, Journal of Industrial and Engineering Chemistry, vol. 17, pp 377–38, 2011.

Pătrăşcioiu C., Tehnici numerice de optimizare, MatrixROm, Bucuresti, 2005. International Multidisciplinary Scientific GeoConfenferences SGEM 2015 www.sgem.org

Agirre I., Garcı´a I., Requies J., Barrio V.L., Güemez M.B., Cambra J.F., Arias P.L., Glycerol acetals, kinetic study of the reaction between glycerol and formaldehyde , Biomass and bioenergy, Spain, vol. 35, pp. 3636-3642, 2011.

De Torres M., Gonzalo J. , Mayoral J. A., Pires E., Santos M., Glycerol ketals: Synthesis and profits in biodiesel blends, Fuel, Spain, vol. 94, pp. 614–616, 2012. International Multidisciplinary Scientific GeoConfenferences SGEM 2015 www.sgem.org 15th International Multidisciplinary Scientific GeoConferences SGEM2015

Esteban J. , Ladero M. , García -Ochoa F., Kinetic modelling of the solventless synthesis of solketal with a sulphonic ion exchange resin, Chemical Engineering Journal, Spain, vol. 269, pp. 194–202, 2015.

Oprescu E. -E., Dragomir R.-E., Radu E., Radu A., Velea S., Bolocan I., Stepan E., Rosca P., Performance and emission characteristics of diesel engine powered with diesel– glycerol derivatives blends, Fuel Processing Technology, Romania, vol. 126, pp. 460-468, 2014.

Hong X., McGiveron O., Kolah A.K., Orjuela A., Peereboom L., Lira C.T., Miller D.J., Reaction kinetics of glycerol acetal formation via transacetalization with 1,1- diethoxyethane, Chemical Engineering Journal, vol. 222, pp. 374–381, 2013.

Capeletti M.R., Balzano L., de la Puente G., Laborde M., Sedran U., Synthesis of acetal (1,1-diethoxyethane) from ethanol and acetaldehyde over acidic catalysts, Applied Catalysis A: General, vol. 198, pp. L1-L4 , 2000.

Agirre I., Güemez M.B., Ugarte A., Requies J., Barrio V.L., Cambra J.F., Arias P.L., Glycerol acetals as diesel additives: Kinetic study of the reaction between glycerol and acetaldehyde, Fuel Processing Technology, vol. 116, pp. 182–188, 2013.

Reddy P. S., Sudarsanam P. , Mallesham B. , Raju G. , Reddy B. M., Acetalisation of glycerol with acetone over zirconia and promoted zirconia catalysts under mild reaction conditions, Journal of Industrial and Engineering Chemistry, vol. 17, pp 377–38, 2011.

Pătrăşcioiu C., Tehnici numerice de optimizare, MatrixROm, Bucuresti, 2005. International Multidisciplinary Scientific GeoConfenferences SGEM 2015 www.sgem.org