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THE MECHANISM OF TRANSPASSIVE DISSOLUTION OF ASS N25 AUSTENITIC STAINLESS STEEL IN SULPHURIC ACID SOLUTION

Emeritus. Dr. Mirjana Metikos-Hukovic

First published: 2012-06-18https://doi.org/10.5593/sgem2012/s02.v2041View metrics

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Title
THE MECHANISM OF TRANSPASSIVE DISSOLUTION OF ASS N25 AUSTENITIC STAINLESS STEEL IN SULPHURIC ACID SOLUTION
Authors
Emeritus. Dr. Mirjana Metikos-Hukovic
Proceedings
SGEM International Multidisciplinary Scientific GeoConference EXPO Proceedings; SGEM2012 12th International Multidisciplinary Scientific GeoConference
Publisher
Stef92 Technology
Year
2012
Pages
313 - 324 pp
ISSN
1314-2704
ISBN
Not available yet
Language
en
Publication type
Conference Paper
Keywords
References42
  1. Song G., Transpassivation of Fe-Cr-Ni stainless steels , Corrosion Science, vol. 47, no. 8, pp. 1953–1987, 2005.

  2. Macdonald D. D., On the tenuous nature of passivity and its role in the isolation of HLNW, Journal of Nuclear Materials, vol. 379, no. 1–3, pp. 24–32, 2008.

  3. MacDonald D. D., On the existence of our metals-based civilization I. Phase- space analysis , Journal of the Electrochemical Society, vol. 153, no. 7, pp. B213–B224, 2006.

  4. Zhang L. and Macdonald D. D., Segregation of alloying elements in passive systems—II. Numerical simulation , Electrochimica Acta, vol. 43, no. 18, pp. 2673–2685, 1998.

  5. Betova I., Bojinov M., Laitinen T., Mäkelä K., Pohjanne P., and Saario T ., The transpassive dissolution mechanism of highly alloyed stainless steels I. Experimental results and modelling procedure , Corrosion Science, vol. 44, no. 12, pp. 2675–2697, 2002.

  6. Betova I., Bojinov M., Tzvetkoff T., Oxidative dissolution and anion-assisted solubilisation in the transpassive state of nickel–chromium alloys , Electrochimica Acta 49 2295–2306, 2004.

  7. Bojinov M., Fabricius G., Laitinen T., Saario T. Transpassivity mechanism of iron-chromium-molybdenum alloys studied by AC impedance, DC resistance and RRDE measurements, Electrochimica Acta 44 4331-4343, 1999.

  8. Macdonald D. D., Passivity—the key to our metals-based civilization , Pure and Applied Chemistry, vol. 71, no. 6, pp. 951–978, 1999.

  9. Martinez S., Metikoš-Hukovi ć M., Lajçi N., Passivity of nitrogen-bearring stainless steel in acid solution, Passivation of metals and semiconductors, and properties of thin oxide layers , The 9th International Symposium on the Passivation of Metals and Semiconductors and the Properties of Thin Oxide Layers, Paris, 103, 2006.

  10. Petrović Ž., Lajçi N., Metikoš-Hukovi ć M., Babi ć R., Barrier and semiconducting properties of thin anodic films on chromium in an acid solution , J Solid State Electrochem, vol. 15 pp. 1201–1207,2011.

  11. Bardwell J. A., Sproule G. I., MacDougall B., Graham M. J., Davenport A. J., and Isaacs H. S., In situ XANES detection of Cr(VI) in the passive film on Fe- 26Cr, Journal of the Electrochemical Society, vol. 139, no. 2, pp. 371–373, 1992 SGEM2012 - DOI: 10.5593/sgem2012 www.sgem.org Hydrogeology, Engineering Geology and Geotechnics

  12. Olefjord I., Mater. Sci. Eng., Vol. 42, , pp. 161, 1980

  13. Sato N., in: R.P. Frankenthal, J. Kruger (Eds.), Passivity of Metals , The Electrochemical Society, Pennington, NJ, pp. 29, 1978.

  14. Morrison S.R., Electrochemistry at Semiconductor Electrodes , Chap. 5, Plenum Press, New York, 1980.

  15. Dean M.H., Stimming U., The electronic properties of disordered passive films , Corros. Sci. 29 (1989) 199.

  16. Simoes A.M.P., Ferreira M.G.S., Rondot B., Cunha Belo M. da, Study of Passive Films Formed on AISI 304 Stainless Steel by Impedance Measurements and Photoelectrochemistry, J. Electrochem. Soc. vo. 137 pp. 82-87, 1990.

  17. Metikoš-Hukovic M., Babić R., Gruba ć Z., Petrovi ć Ž., Lajçi N. , High corrosion resistance of austenitic stainless steel alloyed with nitrogen in an acid solution, Corrosion Science vol. 53 2176–2183, 2011.

  18. Macdonald D.D., Sun A., Priyantha N., Jayaweera P., J. An electrochemical impedance study of Alloy-22 in NaCl brine at elevated temperature: II. Reaction mechanism analysis, Electroanal. Chem. Vol. 572 pp. 421-431, 2004.

  19. Cho E.A., Kwon H.S., Macdonald D.D., Photoelectrochemical analysis on the passive film formed on Fe–20Cr in pH 8.5 buffer solution , Electrochim. Acta vol. 47 pp. 1661-1668, 2002.

  20. Hakiki N.E., Montemor M.F., Ferreira M.G.S., Cunha Belo M. da, Semiconducting properties of thermally grown oxide films on AISI 304 stainless steel, Corros. Sci. vol. 42 pp. 687-702, 2000.

  21. Ahn S.J., Kwon H.S., Macdonald D.D., Role of Chloride Ion in Passivity Breakdown on Iron and Nickel, J. Electrochem. Soc. vol. 52 B482-490, 2005. SGEM2012 - DOI: 10.5593/sgem2012 www.sgem.org 12th International Multidisciplinary Scientific GeoConference SGEM 2012 SGEM2012 - www.sgem.org

  22. Song G., Transpassivation of Fe-Cr-Ni stainless steels , Corrosion Science, vol. 47, no. 8, pp. 1953–1987, 2005.

  23. Macdonald D. D., On the tenuous nature of passivity and its role in the isolation of HLNW, Journal of Nuclear Materials, vol. 379, no. 1–3, pp. 24–32, 2008.

  24. MacDonald D. D., On the existence of our metals-based civilization I. Phase- space analysis , Journal of the Electrochemical Society, vol. 153, no. 7, pp. B213–B224, 2006.

  25. Zhang L. and Macdonald D. D., Segregation of alloying elements in passive systems—II. Numerical simulation , Electrochimica Acta, vol. 43, no. 18, pp. 2673–2685, 1998.

  26. Betova I., Bojinov M., Laitinen T., Mäkelä K., Pohjanne P., and Saario T ., The transpassive dissolution mechanism of highly alloyed stainless steels I. Experimental results and modelling procedure , Corrosion Science, vol. 44, no. 12, pp. 2675–2697, 2002.

  27. Betova I., Bojinov M., Tzvetkoff T., Oxidative dissolution and anion-assisted solubilisation in the transpassive state of nickel–chromium alloys , Electrochimica Acta 49 2295–2306, 2004.

  28. Bojinov M., Fabricius G., Laitinen T., Saario T. Transpassivity mechanism of iron-chromium-molybdenum alloys studied by AC impedance, DC resistance and RRDE measurements, Electrochimica Acta 44 4331-4343, 1999.

  29. Macdonald D. D., Passivity—the key to our metals-based civilization , Pure and Applied Chemistry, vol. 71, no. 6, pp. 951–978, 1999.

  30. Martinez S., Metikoš-Hukovi ć M., Lajçi N., Passivity of nitrogen-bearring stainless steel in acid solution, Passivation of metals and semiconductors, and properties of thin oxide layers , The 9th International Symposium on the Passivation of Metals and Semiconductors and the Properties of Thin Oxide Layers, Paris, 103, 2006.

  31. Petrović Ž., Lajçi N., Metikoš-Hukovi ć M., Babi ć R., Barrier and semiconducting properties of thin anodic films on chromium in an acid solution , J Solid State Electrochem, vol. 15 pp. 1201–1207,2011.

  32. Bardwell J. A., Sproule G. I., MacDougall B., Graham M. J., Davenport A. J., and Isaacs H. S., In situ XANES detection of Cr(VI) in the passive film on Fe- 26Cr, Journal of the Electrochemical Society, vol. 139, no. 2, pp. 371–373, 1992 SGEM2012 - DOI: 10.5593/sgem2012 www.sgem.org Hydrogeology, Engineering Geology and Geotechnics

  33. Olefjord I., Mater. Sci. Eng., Vol. 42, , pp. 161, 1980

  34. Sato N., in: R.P. Frankenthal, J. Kruger (Eds.), Passivity of Metals , The Electrochemical Society, Pennington, NJ, pp. 29, 1978.

  35. Morrison S.R., Electrochemistry at Semiconductor Electrodes , Chap. 5, Plenum Press, New York, 1980.

  36. Dean M.H., Stimming U., The electronic properties of disordered passive films , Corros. Sci. 29 (1989) 199.

  37. Simoes A.M.P., Ferreira M.G.S., Rondot B., Cunha Belo M. da, Study of Passive Films Formed on AISI 304 Stainless Steel by Impedance Measurements and Photoelectrochemistry, J. Electrochem. Soc. vo. 137 pp. 82-87, 1990.

  38. Metikoš-Hukovic M., Babić R., Gruba ć Z., Petrovi ć Ž., Lajçi N. , High corrosion resistance of austenitic stainless steel alloyed with nitrogen in an acid solution, Corrosion Science vol. 53 2176–2183, 2011.

  39. Macdonald D.D., Sun A., Priyantha N., Jayaweera P., J. An electrochemical impedance study of Alloy-22 in NaCl brine at elevated temperature: II. Reaction mechanism analysis, Electroanal. Chem. Vol. 572 pp. 421-431, 2004.

  40. Cho E.A., Kwon H.S., Macdonald D.D., Photoelectrochemical analysis on the passive film formed on Fe–20Cr in pH 8.5 buffer solution , Electrochim. Acta vol. 47 pp. 1661-1668, 2002.

  41. Hakiki N.E., Montemor M.F., Ferreira M.G.S., Cunha Belo M. da, Semiconducting properties of thermally grown oxide films on AISI 304 stainless steel, Corros. Sci. vol. 42 pp. 687-702, 2000.

  42. Ahn S.J., Kwon H.S., Macdonald D.D., Role of Chloride Ion in Passivity Breakdown on Iron and Nickel, J. Electrochem. Soc. vol. 52 B482-490, 2005. SGEM2012 - DOI: 10.5593/sgem2012 www.sgem.org 12th International Multidisciplinary Scientific GeoConference SGEM 2012 SGEM2012 - www.sgem.org

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