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LITHOLOGICAL AND HYDROCHEMICAL FACTORS CONTROLLING THE OCCURRENCE OF HIGH FLUORIDE AND IRON LEVELS IN ESTONIAN AQUIFER SYSTEMS

PhD. Enn Karro, MSc. Kaire Veeperv

First published: 2017-06-20https://doi.org/10.5593/sgem2017/31/s12.054View metrics

Abstract

The drinking water demand of most Estonian communities is covered by groundwater abstracted from the sedimentary rocks. Due to the climate and small population, EstoniaпїЅs fresh water resources are sufficient. However, Estonia faces a number of problems with natural groundwater quality in some areas. Fluoride concentrations up to 7 mg/l are recorded in western Estonia and deeper portion of the Silurian-Ordovician aquifer system, which consists of diverse limestone and dolomite. Fluorine contents in carbonate rocks vary from 70 to 1030 mg/kg and the increase of the clay fraction is followed by the increase in the fluorine content in the carbonate rocks. Batch dissolution tests showed that the amount of leached fluoride is proportional to the fluorine content in rock samples. Total iron concentrations as high as 26 mg/l have been determined in terrigenous Middle Devonian aquifer system in places. Those high iron values are caused by high Fe2+ contents, which points to the domination of reducing conditions in groundwater. FeO and Fe2O3 contents in aquifer forming rocks increase by the increasing of the silt and clay content of the terrigenous rocks. However, the highest leached Fe concentrations (up to 1.5 mg/l) were detected from the sandy sedimentary rocks, where large pores enhance the circulation of water and intensive leaching of iron.

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Publication details

Title
LITHOLOGICAL AND HYDROCHEMICAL FACTORS CONTROLLING THE OCCURRENCE OF HIGH FLUORIDE AND IRON LEVELS IN ESTONIAN AQUIFER SYSTEMS
Authors
PhD. Enn Karro, MSc. Kaire Veeperv
Proceedings
SGEM International Multidisciplinary Scientific GeoConference EXPO Proceedings; 17th International Multidisciplinary Scientific GeoConference SGEM2017, Water Resources. Forest, Marine and Ocean Ecosystems
Publisher
STEF92 Technology
Year
2017
Pages
429-436
SWS Citekey
Karro201712429436
ISSN
1314-2704
ISBN
978-619-7408-04-1
Language
en
Publication type
Conference Paper
Keywords
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