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ELECTROCHEMICAL METHODS AS PROMISING ROUTES FOR NANOSTRUCTURATION AND FUNCTIONALIZATION OF MATERIALS AND BIOMATERIALS

Lidia Benea

First published: 2018-06-20https://doi.org/10.5593/sgem2018/6.1/s24.026View metrics

Abstract

Electrochemical method for the preparation of high-quality nanostructured surfaces and functionalization through active biomolecules electrodepositions are highlighted in this work. There are two applied electrochemical methods in order to obtain hybrid and nanocomposite structured layers or advanced functionalization of material surfaces: (i) electrochemical oxidation or anodization of materials resulting nanoporous or nanostructured oxide films and (ii) direct electrochemical synthesis by electrocodeposition process of nanocomposite layers. The main goal of the present paper is to make a summary of results obtained from applying electrochemical surface modification techniques in obtaining advanced functional surfaces and their properties characterization in terms of surface morphology, structure (SEM-EDX, XRD), roughness and layers thicknesses, corrosion, tribocorrosion as well as the mechanical properties as nanohardness or wear resistance. Electrodeposition and the combination of electrodeposition with other electrochemical processes as controlled oxide growth by anodization can lead to a large class of nanocomposite, nanostructured or hybrid layers and composite coatings (films) on different support materials and structures necessary for a future based on nanotechnology and nanomaterials to improve the surface properties of materials face of aggressive environments and degradation processes. Improving surface properties of materials for corrosion and tribocorrosion functional systems in specific environments give more valuable industrial and biomedical applications by increasing the efficiency and life cycle.

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Publication details

Title
ELECTROCHEMICAL METHODS AS PROMISING ROUTES FOR NANOSTRUCTURATION AND FUNCTIONALIZATION OF MATERIALS AND BIOMATERIALS
Authors
Lidia Benea
Proceedings
SGEM International Multidisciplinary Scientific GeoConference EXPO Proceedings; 18th International Multidisciplinary Scientific GeoConference SGEM2018, Nano, Bio and Green - Technologies for a Sustainable Future
Publisher
STEF92 Technology
Year
2018
Pages
191-198
SWS Citekey
BENEA201824191198
ISSN
1314-2704
ISBN
978-619-7408-50-8
Language
en
Publication type
Conference Paper
Keywords
References13
  1. Benea L.; Corrosion and Corrosion protection - From theory to practice, Ed. Academica, Roumania, 2017, ISBN: 978-973-8937-99-4;

  2. Vargel C., Corrosion de l'aluminium, Ed. Dunod, Fr., 1999. ISBN: 2-10-004191-6.

  3. Poinern G. E. J., Ali N., Fawcett D., Progress in nano-engineerd anodic aluminum oxide membrane development, Materials, 2011, pp 487-526;

  4. Poinern G. E. J., Le X. T., Hager M., Becker T., Fawcett D., Electrochemical synthesis, characterization, and preliminary biological evaluation of an anodic aluminum oxide membrane with a pore size of 100 nanometers for a potential cell culture substrate, American Journal of Biomedical Engineering, 3(6), 2013, pp 119-131;

  5. Dumitrascu V., Benea L., Influence of the Anodic Oxidation Treatment on the Corrosion Behaviour of Aluminium and Aluminium Alloys. The Annals of Dunărea de Jos University of Galati. Fascicle IX. Metallurgy and Materials Science, N°. 3 – 2015, pp 10-16;

  6. Dumitrascu V. M., Benea L., Improving the corrosion behavior of 6061 aluminum alloy by controlled anodic formed oxide layer. Revista de Chimie, 2017, pp 77-80;

  7. Benea L., Danaila E., Ponthiaux P., Effect of titania anodic formation and hydroxyapatite electrodeposition on electrochemical behaviour of Ti–6Al–4V alloy under fretting conditions for biomedical applications. Corrosion Science, 91, 2015, pp 262-271;

  8. Benea L., Mardare E., Mardare M., Celis J. P., Preparation of titanium oxide and hydroxyapatite on Ti-6Al-4V alloy surface and electrochemical behaviour in bio-simulated fluid solution. Corrosion Science, 80, 2014, pp 331-338;

  9. Benea L., Celis J.-P., Effect of Nano-TiC Dispersed Particles and Electro-Codeposition Parameters on Morphology and Structure of Hybrid Ni/TiC Nanocomposite Layers, Materials 9(4), 2016, pp 269-286;

  10. Pavlov A. I., Benea L., Celis J.-P., Vazquez L., Influence of nano-TiO2 co-deposition on the morphology, microtopography and crystallinity of Ni/Nano-TiO2 electrosynthesized nanocomposite coatings. Digest Journal of Nanomaterials and Biostructures. Vol. 8, No. 3, 2013, pp 1043 – 1050;

  11. Benea L., Danaila E., Celis J.-P., Influence of electro-co-deposition parameters on nano-TiO2 inclusion into nickel matrix and properties characterization of nanocomposite coatings obtained. Materials Science and Engineering: A, 610, 2014, pp 106-115;

  12. Benea L., Nanocomposite Layers Obtained by Electro-Co-Deposition: Corrosion and Tribocorrosion Properties, Solid State Phenomena, 227, 2015, pp 243-246;

  13. Benea L., Danaila E., Nucleation and growth mechanism of Ni/TiO2 nanoparticles electro-codeposition. Journal of the Electrochemical Society, 163 (13), 2016, pp D655 - D662.

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