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FEATURES OF ZIRCONIUM ION ADSORPTION BY SODIUM MODIFIED TITANIUM DIOXIDE
Abstract
The mechanism for the selective adsorption of zirconium ions in a highly acidic medium by sodium-modified titanium dioxide was proposed. The mechanism of adsorption of zirconium ions in an acidic medium by this adsorbent is similar to the mechanism of adsorption of strontium ions in a neutral medium. The selectivity of Na-TiO2 is due to the positively charged surface of the adsorbent in the highly acidic medium.
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Vasylyeva H., Mironyuk I., Strilchuk M., Maliuk I., Tryshyn V. A new way to ensure selective zirconium ion adsorption. Radiochimica Acta, vol.109 (12), 2021. DOI: 10.1515/ract-2021-1083
Vasylyeva H., Mironyuk I., Mykytyn I.. et al. Application of titanium dioxide for zirconium ions adsorption and separation from a multicomponent mixture. Physics and Chemistry of Solid State, vol. 22(3), pp. 460�469, 2021. DOI: 10.15330/pcss.22.3.460-469
Mironyuk I., Mykytyn I., Vasylyeva H., Savka Kh. Sodium-modified mesoporous TiO2: sol-gel synthesis, characterization, and adsorption activity toward heavy metal cations. Journal of Molecular Liquids, vol.316 (10), 113840, 2020. https://www.doi.org/DOI: 10.1016/j.molliq.2020.113840
Mironyuk I., Kaglyan A., Vasylyeva H., Mykytyn I., Gudkov D., Turovska L. Investigation of the chemical and radiation stability of titanium dioxide with surface arsenate groups during 90Sr adsorption, Journal of Environmental Radioactivity, vol. 251�252, 106974, 2022. DOI: 10.1016/j.jenvrad.2022.106974
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