Scholarly record
LEACHING OF LATERITIC NICKEL ORES OF KARACAM (ESKISEHIR-TURKEY) WITH HYDROCHLORIC ACID
Abstract
In this study, nickel extraction from Karaçam (Eskisehir) region laterites by hydrochloric acid leaching is ai med. The mineralogical analysis showed that the ore sample contains goethite, hema tite, wustite, retgers ite, gaspeite and clay type minerals together with quartz. The effects of various parameters such as leaching time, stirring speed, acid concentration and leaching temperature on nickel recovery were determined. The shrinking core model was applied to the results of experime nts investigating the effects of leaching temperature range of 40–90 °C. Two equations were applied from obtained results from each temperature value. Their correlation coefficients for each temperature are calculated. These results i ndicate that the dissolu tion rate of Ni is controlled by diffusion. The activation en ergy (Ea) for the dissolution reaction was calculated as 74.52 kJ/mol. Arrhenius constant was calculated to be 8.9633 s−1.
Publication Impact Profile
Publication details
References21
Dalvi A.D., Bacon W.G. & Osborne, R.C. The Past and the Future of Nickel Laterites, PDAC 2004 International Conven tion, Trade Show & Investors Exchange, Canada, p. 27, 2004.
Hawkins M.J. Recovering cobalt from primary sources and secondary sources, Journal of Metals, 50(10), pp. 46–50, 1998. Mineral Processing
Piret N.L. Enhancing Cobalt Recovery from Primary and Secondary Resources (Commentary), Journal of Metals, 50(10), pp. 42–4,1998.
Chen T. Physicochemical Properties of Nickel and Cobalt Sulphate Solutions of Hydrometallurgical Relevance, Murdoch Un iversity Western Aust ralia, B.Sc thesis, p.189, 2003.
Deepatana A. Tang, J.A. & Valix, M. Co mparative study of chelating ion exchange resins for metal recovery from bioleaching of nickel laterite ores, Minerals Engineering, 19, pp. 1280–1289, 2006.
Zainol Z. The development of a resin-in-pulp process for the recovery of nickel and cobalt from laterite leach sl urries, MSc thesis, Murdoch Un iversity, Western Australia, p. 258, 2005.
Chander S. Atmospheric Pressure Leaching of nickeliferrous laterites in acidic Media, Trans. Indian Ins. Metals, 35, pp 547-554, 1982.
Tang J. & Valix M. Leachability of Low Grade Nickel Laterite Ores in Organic Acids, 9th APCChE Congress and CHEMECA 2002, New Zealand, p. 525, 2002.
Sukla L.B. & Panchanadikar V. Biolea ching of lateritic nickel ore using a heterotrophic micro-organism, Hydrometallurgy, Vol. 32, Issue 3, pp 373-379, 1993.
Sukla L.B. Swamy K.M. Narayana K.L. Kar R.N. & Panchanadikar V.V. Bioleaching of Sukinda Laterite Using Ultrason ics”, Hydrometallurgy, Vol. 37, Issue 3, pp. 387–391, 1995.
Jacson E. & Lloyd K.J. Enhanced Hydroc hloric Acid Leaching of Nickel, Minerals Eng., Vol 13, No: 14-15, pp. 1565-1572, 2000.
Georgiou D. V.& Papangelakis G. Sulphuric acid pressure leaching of a limonitic laterite: chemistry and kinetics, Hydrometallurgy, 49, pp. 23-46, 1998.
Agacayak T. Beneficiation of Karacam (Eskisehir) Lateritic Nickel Ore by Physical and Chemical Methods, PhD thesis, Selcuk University, Turkey, 2008.
Agacayak T. Aydoğ an S. & Zedef V. Dissolution of Lateritic Nickel Ore in Sulphuric Acid Medium with Potassium Dichromate, Modern Management of Mine Producing, Geology and Environmental Prot ection SGEM 2008, Bulgaria, vol:1, pp. 51–58, 2008.
Agacayak T. & Zedef V. Dissolution Ki netics of Lateritic Iron Ore in Sulphuric Acid Medium, Modern Management of Mi ne Producing, Geology and Environmental Protection SGEM 2009, Bulgaria, vol:1, pp. 397–404, 2009.
Buyukakinci E. & Topkay a Y.A. Extraction of nickel from lateritic ores at atmospheric pressure with agitation leaching, Hydrometallurgy, 97, pp.33–38, 2009.
Arslan F. Özer Ö. Perek K.T. Gürkan, V. & Önal, G. Dissolution of lateritic ore in acidic media, Proceedings of International Mineral Processing Congress, IMPC 2006,Turkey, pp. 1500-1504, 2006.
Agatzini-Leonardou S. & Zafiratos I.G. Beneficiation of a Greek serpentinic nickeliferous ore Part II. sulfuric acid heap and agitation leaching, Hydrometallurgy, 74, pp. 267-275, 2004.
Curlook W.Direct atmospheric leaching of saprolitic nickel laterites with sulfuric acid, In: Imrie W.P., Lane D.M. (Eds.), Inte rnational Laterite Nickel Symposium. TMS, Warrendale, pp. 385–398, 2004.
Habashi F.Principles of Extractive Metallurgy, Gordon and Breach, New York, 1, pp: 153–163, 1969.
Levenspiel O. Chemical Reaction Engineering, 2nd ed., Jhon Wiley and Sons, New York, USA, pp: 566-586, 1999.
View or Download full articleAccess options
SWS access login
Login as SWS Scientific CommitteeLogin as SWS Scientific PartnerLogin as SWS AuthorAuthors and approved SWS contributors will read and export their own linked papers after identity matching by SWS profile, email and SGEM GlobalID.
For librarian assistance: [email protected]
Purchase Instant Access
- Article can be downloaded after successful payment.
- Article may be used according to SWS library access terms.
- Article cannot be redistributed.
