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RECOVERY OF PGMS FROM MINE SLUDGE BY LEACHING

Willie Nheta, Kutullo Mapotsane

First published: 2017-06-20https://doi.org/10.5593/sgem2017/11/s04.126View metrics

Abstract

South Africa host massive deposits of Platinum Group Metals (PGMs) in the Igneous Bushveld Complex. These deposits have been mined for a long time and in the process Mine sludge has been produced. It has been piled up and there is need to recover PGMs locked in it. The conventional way of processing PGMs has proved to be very difficult due to ultra-fines in the sludge that causes major loses during flotation. An alternative hydrometallurgical process for recovery of PGMs from a mine sludge by leaching using a mixture of hydrochloric acid and different oxidizing agents was investigated. It was found that the mine sludge contained 8.93 g/t Pt, 6.99 g/t Pd, 2.79 g/t Ru and minor percentages of Rh, Ir, and Au. It had a particle size distribution (PSD) of 84.64% passing 38 microns. Major mineral phases present are sphalerite, chalcopyrite, pentlandite, covellite, bornite, chromite, and silica as the main gangue. HCL + H2O2 (1:1) combination managed to leach all the PGMs and gold. HCL + Ferric Chloride (1:1) combination managed to leach Pt, Rh and Ru very well but it could not leach Pd. Further investigation on the optimization of the leaching conditions is being done.

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Publication details

Title
RECOVERY OF PGMS FROM MINE SLUDGE BY LEACHING
Authors
Willie Nheta, Kutullo Mapotsane
Proceedings
SGEM International Multidisciplinary Scientific GeoConference EXPO Proceedings; 17th International Multidisciplinary Scientific GeoConference SGEM2017, Science and Technologies in Geology, Exploration and Mining
Publisher
STEF92 Technology
Year
2017
Pages
987-994
SWS Citekey
Nheta20174987994
ISSN
1314-2704
ISBN
978-619-7105-98-8
Language
en
Publication type
Conference Paper
Keywords
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