Scholarly record
STUDY OF THE KINETICS OF THERMAL DEGRADATION OF POLYMER COMPOSITES BASED ON POLYVINYLCHLORIDE FILM AND BIOPOLYMER FILLER
Abstract
In order to reduce the negative impact of PVC on the environment, it is becoming popular to produce composite materials based on PVC filled with various natural fillers. For example, bentonite as filler in a polymer matrix can absorb volatile toxic components and accelerate the degradation of PVC. Also in this paper, natural polysaccharides pectin and starch are considered as fillers. Pectin and starch are also capable of accelerating biodegradation of PVC. Nevertheless, the thermal stability of the resulting polymer composites is also of interest. For these polymeric composites, the thermal stability was studied by thermogravimetry, the destruction mechanism was studied, and the kinetic parameters of the thermal destruction were determined.
Publication Impact Profile
Publication details
References13
Long Yu, Biodegradable Polymer Blends and Composites from Renewable Resources, John Wiley & Sons, 2009, 400 p.
McGlashan St. A., Halley P. J., Preparation and characterisation of biodegradable starch based nanocomposite materials, Polymer Science in Queensland: Celebrating 40 Years of Research, Vol.52, Is.11, pp 1767-1773, 2003.
Lu D. R., Xiao C. M., Xu S. J., Starch-based completely biodegradable polymer materials, eXPRESS Polymer Letters, Vol.3, No.6, pp 366–375, 2009.
Vollova K., Uspenskaya M., Sivtsov E., Belukhichev E. The study of polymer composites based on polyvinylchloride film and biopolymer filler//International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM, IET - 2017, Vol. 17, No. 41, pp. 225-230
Tetto JA, Steeves DM, Welsh EA, Powell BE. Biodegradable poly(1-caprolactone)/clay nanocomposites. ANTEC’99. pp 1628 – 32.
Lee SR, Park HM, Lim HL, Kang T, Li X, Cho WJ, Ha CS. Microstructure, tensile properties, and biodegradability of aliphatic polyester/clay nanocomposites / Polymer, vol. 43, pp 2495 – 500, 2002.
Sinha Ray S, Yamada K, Okamoto M, Ogami A, Ueda K. New polylactide/layered silicate nanocomposites. 3. High performance biodegradable materials / Chem Mater, vol. 15, pp 1456 – 65, 2003.
Uspenskaya, M.V., Sirotinkin, N.V., Yatsenko, S.V., Masik, I.V., Formulations based on hollow glass spheres and polyurethane foams, Russian Journal of Applied Chemistry, 78(5), с. 830-833, 2005.
Zakharova, M., Uspenskaya, M.V., Podshivalov, A.A., The influence of the bentonite particles content on operating properties of gelatin/starch/glycerol/bentonite biocomposite films, International Multidisciplinary Scientific GeoConference Surveying Geology and Mining Ecology Management, SGEM, 17(51), с. 961-966, 2017.
Chrissafis, K.; Bikiaris, D. Can nanoparticles really enhance thermal stability of polymers? Part I: An overview on thermal decomposition of addition polymers / Themochim. Acta, vol. 523, pp 1–24, 2011.
McNeill, I.C.; Memetea, L.; Cole, W.J. A study of the products of PVC thermal degradation / Polym. Degrad. Stabil., vol. 49, pp 181–191, 1995.
Poerschmann J., Weiner B., Woszidlo, S., Koehler R., Kopinke F.D. Hydrothermal carbonization of poly(vinyl chloride)/ Chemosphere, vol. 119, pp 682–689, 2015.
Leo Reich, L. Z Pollara, S.S Stivala Computer-determined kinetic parameters from TG curves. Part XIII / Themochim. Acta, vol. 90, pp 189-193, 1985.
Citing literature
Number of times cited according to Crossref: 1
View or Download full articleAccess options
SWS access login
Login as SWS Scientific CommitteeLogin as SWS Scientific PartnerLogin as SWS AuthorAuthors and approved SWS contributors will read and export their own linked papers after identity matching by SWS profile, email and SGEM GlobalID.
For librarian assistance: [email protected]
Purchase Instant Access
- Article can be downloaded after successful payment.
- Article may be used according to SWS library access terms.
- Article cannot be redistributed.
