Scholarly record
DISSOLUTION OF LATERITIC NICKEL ORE IN SULPHURIC ACID MEDIUM WITH POTASSIUM DICHROMATE
Abstract
In this study, leaching of Ni and Fe in suphuric acid medium with K2Cr2O7 was investigated. The samples of the lateritic nickel ore were taken from Karacam (Eskisehir) region of Turkey. Mineralogical investigations showed that the ore sample contains, goethite, hematite, wustite, retgersite, gaspeite and clay type minerals together with quartz. The shrinking core model was applied to the results of experiments investigating the effects of leaching temperature range of 50–96 ◦C. Two equations were applied from obtained results from each temperature value. Their correlation coefficients for each temperature are calculated. These results indicate that the dissolution rate of Ni is controlled by diffusion. The activation energy for the leaching process was found to be 68.43 kJ/mol and the Arrhenius constant was calculated to be 8.231 s−1.
Publication details
References13
USGS, "Mineral Commodity Summaries" 2007. htpp://minerals.usgs.gov/minerals/pubs/commodity/nickel/nickemcs07.pdf.
Georgiou, D, "Kinetics of nickel dissolution during sulphuric acid pressure leaching of a limonitic laterite" Department of Chemical Engineering and Applied Chemistry University of Toronto, Msc. Thesis, 1995.
Han, K.N.& Meng X. "The leaching behavior of nickel and cobalt from metals and ores" - A Review, The Paul Queneau International Symp. Extractive Metallurgy of Copper, Nickel and Cobalt, Volume I: Fundamental Aspects, Eds. R.G. Reddy & R.N. Weizenbach, (TMS), pp. 709-731, 1993.
Moskalyk R.R. & Alfantazi A.M., "Nickel Latente Processing and Electrowinning Practice", Minerals Eng., 1 5, pp:593-605, 2002.
Arslan F.,Perek K.T.& flnal G.,. "Acidic Leaching of Turkish Lateritic Nickel Ore", Sohn International Symposium on Advanced Processing of Metals and Materials, Thermo and physicochemical principles: special materials, aqueous and electrochemical processing, Volume 3, Eds. F. Kongoli, RG. Reddy, San Diego, USA, pp.339-345, 2006.
Yongue-Fouateu R., Ghogomu R.T., Penaye J., Ekodeck G.E., Stendal H. & Colin F., "Nickel and cobalt distribution in the latentes of the Lomie region, south-east Cameroon" Journal of African Earth Sciences, 2006.
Golightly, J.P. "Nickeliferous latente deposits", Econ. Geol. 75, 710-735, 1981.
Georgiou, D. V.& Papangelakis G., "Sulphuric acid pressure leaching of a limonitic laterite: chemistry and kinetics" Hydrometallurgy, 49, pp. 23-46, 1998.
Zainol, Z., 2005 "The development of a resin-in-pulp process for the recovery of nickel and cobalt from laterite leach slurries" MSc thesis, Murdoch University, Western Australia, p:258.
Taylor, A., "Process selection, Nickel/Cobalt pressure acid leaching and Hydrometallurgy forum, ALTA metallurgical services, Melbourne, Perth, Australia, 1997.
Caron M.H., "Fundamental and Practical Factors in Ammonia Leaching of Nickel and Cobalt Ores", J. Metals Trans. AIME, 1 88, pp: 67-90, 1 950.
Reid, J.G., "Laterite ores - nickel and cobalt resources for the future. In: "Nickel '96 Mineral to Market", Kalgoorlie, 1996.
Agacayak, T., 2008., "Karacam (Eskisehir) Lateritik Nikel Cevherinin Fiziksel ve Kimyasal Yantemlerle Zenginlestirilmesi, Selcuk Universitesi, Fen Bilimleri Enstitusu, Doktora Tezi, Konya, Turkiye, 2008.
View or Download full articleAccess options
SWS access login
Login as SWS Scientific CommitteeLogin as SWS Scientific PartnerLogin as SWS AuthorAuthors and approved SWS contributors will read and export their own linked papers after identity matching by SWS profile, email and SGEM GlobalID.
For librarian assistance: [email protected]
Purchase Instant Access
- Article can be downloaded after successful payment.
- Article may be used according to SWS library access terms.
- Article cannot be redistributed.
