Scholarly record
OBTAINING NANOFIBERS BASED ON PEROVSKITE-POLYMER COMPOSITES FOR APPLYING IN SOLAR CELLS
Abstract
Nanofibers have attracted a lot of attention for applying in the third and fourth generation of solar cells to enhance their performance. In this paper, we investigate the possibility of obtaining and using successfully high-quality nanofibers based on perovskite: polymer composites (PPCs) in perovskite solar cells. First, the advantages, challenges and development directions of employing nanofibers as active layers (ALs) in organic solar cells (OSCs) have been reported to establish the principles needed to prepare nanofibers based on PPCs and to determine the expected benefits that can be obtained from their inclusion in perovskite solar cells (PSCs) as ALs, such as enhanced morphology, as well as efficient charge separation, collection and transport. Then, we had to analyze properties of various bulk perovskite-polymer composites used as ALs in PSCs to justify their electrospinning ability and identify the main merits and problems that can be emerged. We found that due to the long diffusion length of charge carriers in perovskite materials, PPCs nanofibers will be promising active layers for improving the performance of PSCs. Furthermore, polymers used in PPCs should simultaneously improve the quality of the perovskite film (stability, morphology and crystallinity) and facilitate formation of the nanofibers. However, the difficulty of spinning the perovskite material remains the main challenge that need to be addressed. Finally, we think PPCs nanofibers or pure perovskite nanofibers will be widely utilized in various electronic and electrical applications.
Publication Impact Profile
Publication details
References11
[1] Zhenhua Y., Maria M., Ying L., Hongfei L., Luana P., Andrea C., Rosalba S., Maria A. I., Onofrio M. M., Dario P., Chang-Yong N., Eyal Z., Miriam R., Electrospun conjugated polymer/fullerene hybrid fibers: photoactive blends, conductivity through tunnelling-AFM, light-scattering, and perspective for their use in bulk-heterojunction organic solar cells, J. Phys. Chem, USA, 122,5, pp 3058–3067,2018.
[2] Guiru S., Liqun S., Haiming X., Jia L., Electrospinning of nanofibers for energy applications, Nanomaterials, Switzerland, 6, 129, 2016.
[3] Bin D., Jianyong Y., Electrospun nanofibers for energy and environmental applications, Springer-Verlag Berlin Heidelberg, pp 525, 2014.
[4] Christoph B., Markus P., Senol Ö., Florian v. T., Ashish L., Thomas F., Markus S., Klas L., Sanjay M., Electrospun hybrid perovskite fibers-flexible networks of one-dimensional semiconductors for light-harvesting applications, ACS Appl. Mater. Interfaces, USA, 11, pp 25163−25169, 2019.
[5] Dongsheng C., Yanyan Z., Electrospun perovskite nanofibers, Nanoscale Research Letters, 12, 2017;
[6] Ayat N. E., Marwan Y. R., Kareem M. G., Nageh K. A. Electrospun lead-free all-inorganic double perovskite nanofibers for photovoltaic and optoelectronic applications, ACS Appl. Nano Mater, USA, 2, 11, pp 7085-7094, 2019.
[7] Ping-Chun T., Jung-Yao C., Ender E., Chu-Chen C., Shih-Huang T., Wen-Chang C., Uniform luminous perovskite nanofibers with color-tunability and improved stability prepared by one-step core/shell electrospinning, Small, 14, 2018;
[8] Gaolin L., Zhenhua J., WeilinW., Zengyong C., Ye Z., Chunhua W., Electrospun PAN/MAPbI3 composite fibers for flexible and broadband photodetectors, Nanomaterials, Switzerland, 9, 50, 2019.
[9] Jiexuan J., Qian W., Zhiwen J., Xisheng Z., Jie L., Haijun B., Zhi-Guo Z., Yongfang L., Shengzhong L., Polymer doping for high-efficiency perovskite solar cells with improved moisture stability, Adv. Energy Mater., 8, 2018.
[10] Tianqi N., Jing L., Rahim M., Jianbo L., Dounya B., Xu Z., Hanlin H., Zhou Y., Aram A., Kui Z., Shengzhong L., Stable high-performance perovskite solar cells via grain boundary passivation, Adv. Mater., 30, 2018.
[11] Chen D., Shuo W., Xu M., Wenhai S., Yu Z., Chengyan W., Ruixin M., Polyvinylpyrrolidone as additive for perovskite solar cells with water and isopropanol as solvents, B. J. Nanotechnol., 10, pp 2374–2382,2019.
Citing literature
Number of times cited according to Crossref: 4
View or Download full articleAccess options
SWS access login
Login as SWS Scientific CommitteeLogin as SWS Scientific PartnerLogin as SWS AuthorAuthors and approved SWS contributors will read and export their own linked papers after identity matching by SWS profile, email and SGEM GlobalID.
For librarian assistance: [email protected]
Purchase Instant Access
- Article can be downloaded after successful payment.
- Article may be used according to SWS library access terms.
- Article cannot be redistributed.

