Scholarly record
POLYLACTIC ACID MODIFIED BY REACTIVE EXTRUSION TECHNOLOGY
Abstract
In recent years there has been an increase in interest in biodegradable polymers. Biopolymers are upcoming competitors for the synthetic polymers with their profound attributes like eco-friendliness and biodegradability. They can be classified as natural biopolymers, chemically synthesized biopolymers, and microbial biopolymers. One of the most widely used chemically synthesized biopolymers is aliphatic polyester polylactic acid (PLA). It is a thermoplastic derived from renewable, organic sources such as corn starch or sugar cane. Although PLA offers a number of advantages such as high strength and high modulus, excellent optical properties, moisture resistance and biocompatibility, this is a quite fragile material. Other disadvantages are poor impact strength and low elongation. One way to improve the unsuitable PLA mechanical properties is to modify the material with additives like plasticizers, fillers etc. In this research, attention is focused on modification of PLA by reactive extrusion technology. Obtained materials were tested by DSC to evaluate changes in transition temperatures of PLA (Tg, Tm) and mechanical properties were tested too. The significant changes in mechanical properties were noticed.
Publication Impact Profile
Publication details
References10
BORRION Aiduan, BLACK Mairi J, MWABONIE Onesmus. Life Cycle Assessment - A Metric for the Circular Economy - 7.1.1 Sustainable Polymers from Renewable Resources. Royal Society of Chemistry (RSC), 2021, p. 153-157. Retrieved from https://app.knovel.com/hotlink/pdf/id:kt012VMRN2/life-cycle-assessment/sustainablepolymers
GEYER. Roland, Jenna R. JAMBECK a Kara Lavender LAW. Production, use, and fate of all plastics ever made. Science Advances 2017, 3(7). ISSN 2375-2548. DOI: 10.1126/sciadv.1700782
NEUGEBAUER D. Graft copolymers with hydrophilic and hydrophobic polyether side chains, Polymer 2007 Vol 48 (17) pp. 4966 - 4973, DOI: 10.1016/j.polymer.2007.06.037.
GEORGIOU, Theoni K. A library of thermoresponsive PEG-based methacrylate homopolymers: How do the molar mass and number of ethylene glycol groups affect the cloud point? Journal of Polymer Science 2021, Vol 59 (3), p. 230-239, DOI: 10.1002/pol.20200720.
CAVUS, Gokhan Synthesis of Some Novel Blends of Polylactide with Polylactide-b- Poly (ethylene glycol) Block Copolymers, Journal of Macromolecular Science, Part A, 2012, Vol 49 (2), p. 164-170, DOI: 10.1080/10601325.2012.642222
AURAS. Rafael. Poly(lactic acid): synthesis. structures. properties. processing. and applications/ edited by Rafael Auras.. [et al.] [online]. Hoboken. N.J.: Wiley, 2010, ISBN 978-047-0293-669. DOI: 10.1002/9780470649848
FINK. Johannes Karl. Reactive extrusion. Reactive polymers Fundamentals and applications [online]. Elsevier 2013, 339 [cit. 2016-10-19]. ISBN 9781455731497. DOI: 10.1016/b978-1-4557-3149-7.00015-2
AL-ITRY Racha, Khalid LAMNAWAR a Abderrahim MAAZOUZ. Reactive extrusion of PLA. PBAT with a multi-functional epoxide: Physico-chemical and rheological properties. European Polymer Journal, 2014, Vol. 58, p. 90-102 [cit. 2017- 01-27]. ISSN 00143057. DOI: 10.1016/j.eurpolymj.2014.06.013
HASSOUNA Fatima, LAACHACHI Abdelghani, CHAPRON David, EL MOUEDDEN Yamna, TONIAZZO Valerie a RUCH David. Development of new approach based on Raman spec-troscopy to study the dispersion of expanded graphite in poly(lactide): Lecture Notes from the 2nd ERCOFTAC Summerschool hel in Stockholm, 10-16 june, 1998. Polymer Degradation and Stability, 2011, Vol. 96(12), p. 2040-2047, DOI: 10.1016/j.polymdegradstab.2011.10.005, ISSN 01413910.
KFOURY Georgio, RAQUEZ Jean-Marie, HASSOUNA Fatima, LECLERE Philippe, TONIAZZO Valerie, RUCH David a DUBOIS Philippe. Toughening of poly(lactide) using polyethylene glycol methyl ether acrylate: Reactive versus physical blending. Polymer Engineering 2015, Vol. 55(6), p. 1408-1419, DOI: 10.1002/pen.24085. ISSN 00323888.
View or Download full articleAccess options
SWS access login
Login as SWS Scientific CommitteeLogin as SWS Scientific PartnerLogin as SWS AuthorAuthors and approved SWS contributors will read and export their own linked papers after identity matching by SWS profile, email and SGEM GlobalID.
For librarian assistance: [email protected]
Purchase Instant Access
- Article can be downloaded after successful payment.
- Article may be used according to SWS library access terms.
- Article cannot be redistributed.

