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DEVELOPMENT OF NOVEL CATALYSTS SYNTHESIZED BY HYDROTHERMAL METHOD

Valentina G. Matveeva

First published: 2018-06-20https://doi.org/10.5593/sgem2018/6.1/s24.022View metrics

Abstract

Last years the use of sub- and supercritical fluids in the catalyst synthesis is a great attention. Because of the unique properties subcritical water allow synthesizing the metal-based catalysts with the desired size, dispersity, structure and morphology of the active phase. In this work, we report the study of the structure of polymer-based Pdcontaining catalysts synthesized by hydrothermal deposition. It is shown that the use of palladium chloride as a metal precursor decreases significantly the specific surface area in comparison with that obtained for palladium acetate because of the formation of the larger metal particles on the support surface. Pd is presented by the Pd0 in all studied samples. The complex Pd/PdO particles were observed in the minor amounts. The hydrothermal synthesis allows obtaining the catalysts with the mean particle size 4-8 nm. Thus, hydrothermal method is the permissive way to synthesize the catalysts with the controllable size, structure, and morphology of the metal nanoparticles.

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Publication details

Title
DEVELOPMENT OF NOVEL CATALYSTS SYNTHESIZED BY HYDROTHERMAL METHOD
Authors
Valentina G. Matveeva
Proceedings
SGEM International Multidisciplinary Scientific GeoConference EXPO Proceedings; 18th International Multidisciplinary Scientific GeoConference SGEM2018, Nano, Bio and Green - Technologies for a Sustainable Future
Publisher
STEF92 Technology
Year
2018
Pages
163-168
SWS Citekey
Matveeva201824163168
ISSN
1314-2704
ISBN
978-619-7408-50-8
Language
en
Publication type
Conference Paper
Keywords
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