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REE GEOCHEMISTRY, MINERALOGY AND ORIGIN OF MANGANESE IN THE ARTOVA OPHIOLITE COMPLEX, YOZGAT (TURKEY)
Abstract
Artova ophiolite complex is located along the North western and east margin in Yozgat (Turkey). The Mn-deposits in the Derbent an d Eymir areas are part of this ophiolite complex. These deposits, both banded and lenticular forms, are hosted by radiolarite and are generally overlying volcanics. Braunite, jacopsite, psilomelane and goethite are main constituents of the manganese ores in Eymir (Sorgun-Yo zgat) and manyetite, manganite, pyrolusite and goethite are main constituents of the manganese ores in Derbent (Mahkeme hill-Yozgat ) areas. The gang mineral in Eymir is just quartz, whereas the gang minerals in Derbent are quartz and calcite. In chondrite normalized REE graphics samples are characterized by highly negative and positive Ce anomalies in both area. Europium shows negative anomaly in all samples. The negative Ce anomaly is typical to submarine hydrothermal deposits and positive Ce anomaly is indicative of hydrogenous deposits. The negative Eu anomaly shows contamination from the continental crust and/or sedime nt contribution via dehydration. Ce values in the Eymir mineralization were computed from the equation of Ce anom=log [3xCeN/(2xLaN+NdN)] and anomalies were found as Ce anom< -0.1 in 8 samples and Ceanom > - 0.1 in 12 samples, whereas th e same values in the Mahkeme Hill mineralization were computed and the anomalies were found as Ce anom< -0.1 in 9 samples and Ce anom > - 0.1 in 5 samples. These values are indicative of both oxic and anoxic sedimentation conditions. Chemica lly, the studied manganese deposits and associated radiolarite are very similar to these formed by hydrothermal – hydrogenous processes.
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