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OBTAINING SORBENTS FROM GLAUCONITE AND GLAUCONITIC SAND OF KAZAKHSTAN

Balgysheva, Beykut, Dalabayeva, Nazgul, Botambay, Aidana, B, Nussip, M., Saduakas

First published: 2016-06-28https://doi.org/10.5593/sgem2016/b12/s04.145View metrics

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Title
OBTAINING SORBENTS FROM GLAUCONITE AND GLAUCONITIC SAND OF KAZAKHSTAN
Authors
Balgysheva, Beykut, Dalabayeva, Nazgul, Botambay, Aidana, B, Nussip, M., Saduakas
Proceedings
SGEM International Multidisciplinary Scientific GeoConference EXPO Proceedings; 16th International Multidisciplinary Scientific GeoConference SGEM2016, Science and Technologies in Geology, Exploration and Mining
Publisher
Stef92 Technology
Year
2016
Pages
1127-1134
ISSN
1314-2704
ISBN
978-619-7105-56-8
Language
en
Publication type
Conference Paper
References32

  1. 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org Mineral Processing

  2. Maryam,T., Hossein, K., Sodeh, S., and Morteza, T, Synthesis and characterization of zeolite NaY using kaolin with different synthesis methods, Clays and Clay Minerals , vol. 62, pp 508518, 2014.

  3. Wilson, M. J., Wilson, L., and Patey, I, The influence of individual clay minerals on formation damage of reservoir sandstones: a critical review with some new insights, Clay minerals, vol. 49, pp 147164, 2014.

  4. Adriaens, R., Vandenberghe, N., and Elsen, J, Natural clay-sized glauconite in the neogene deposits of the campine basin (Belgium), Clays and clay minerals, vol.62, pp 355, 2014.

  5. Muller, F., Drits, V., Planço n, A., and Rober, T.J, Structural transformation of 2:1 dioctahedral layer silicates during dehydroxylation-rehydroxylation reactions, Clays and Clay Minerals, vol. 48, pp 572 585, 2000.

  6. Li, X ., Cai, Y.F ., Hu, X.M ., Huang, Z.C ., and Wang, J.G , Mineralogical characteristics and geological significance of Albian (Early Cretaceous) glauconite in Zanda, southwestern Tibet, China, Clay minerals, vol. 47, pp 4558, 2012.

  7. Pestitschek, B., Gier, S., and Essa, M, Effects of weathering on glauconite: evidence from the abu tartur plateau, Egypt, Clays and clay minerals, vol. 60, pp 76 88, 2012.

  8. Baldermann, A ., Warr, L.N ., Grathoff, G.H ., and Dietzel, M , The rate and mechanism of deep-sea glauconite formation at the ivory coast-ghana marginal ridge, Clays and clay minerals, vol. 61, pp 258276, 2013.

  9. Valanciene, V., Siauciunas, R., and Valancius, Z, Evaluation of glauconite rock color stability during firing, Applied clay science, vol. 99, pp 110118 , 2014.

  10. Huggett, J.M . and Cuadros, J , Glauconite formation in lacustrine/palaeosol sediments, Isle of Wight (Hampshire Basin), UK, Clay minerals, vol. 45, pp 35 49, 2010.

  11. Hassan, M. and El, S.H , Glauconitic clay of El Gidida, Egypt: evaluation and surface modification, Applied clay science, vol.27, pp 219222, 2004.

  12. Chang, S.S., Shau, Y.H., and Wang, M.K, Mineralogy and occurrence of glauconite in central Taiwan, Applied clay science, vol. 42, pp 7480, 2008.

  13. Hassan, M.S. and Baioumy, H.M, Structural and chemical alteration of glauconite under progressive acid treatment. Clays and clay minerals, vol. 54, pp 491499, 2006.

  14. Ehsan, K., Ahmad, A., Hamid, S., and Arash, A, The potential of glauconitic sandstone as a potassium fertilizer for olive plants, Archives of Agronomy and Soil Science, vol.58, pp 983993, 2012.

  15. Kuanysheva, G., Balgysheva, B., Dalabayeva, N, Preperation of low-temperature polyphosphate fertiliser by the addition of serpentine, 22nd Annual Conference, UK, p 11, 2014.

  16. Franus, M. and Bandura, L, Sorption of heavy metal ions from aqueous solution by glauconite, Fresenius environmental bulletin, 23, pp 825 839, 2014. 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org 16th International Multidisciplinary Scientific GeoConference SGEM 2016 Figure 1 and (1a ). XRD patterns of the initial glauconitic and mechanically activated glauconitic. At the bottom – dependence the degree of sorption for Mn 2+ ions mechanically activated mixtures to the concentration of the initial solution for extraction Figure 2. TG and DSC of initial glauconitic concentrate Figure 3. TG and DSC of initial glauconitic sand 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org Mineral Processing Figure 4. The scanning electron microscopy of modified glauconite 2:1 Figure 5. TG and DSC of modified glauconite 2:1 Figure 6. Changing degree of sorption of glauconitic sand for Mn2+, Cu2+, Ni2+ ions from obtained modified form of glauconitic 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org 16th International Multidisciplinary Scientific GeoConference SGEM 2016 Table 1 The contents of manganese, copper, nickel and zinc ions in the solution during the sorption with glauconitic (G) Solution and sample of glauconite Mn2+ Сu2+ Ni2+ Zn2+ Сs, mg/L α, % Сs, mg/L α, % Сs, mg/L α, % Сs, mg/L α, % Initial solution (Сis) 56.7 058.3 051.6 051.2 0 Glauconite : NaH2PO4 = 1:1 (mechanically activated) 7.8 6.2 8.4 5.6 26.4 8,9 2.6 4,9 Raw material (Glauconite) 45.1 0.4 56.5 3.0 43.9 5.0 43.5 5.0 Glauconite, 450°C 47.5 6.3 51.1 2.5 45.1 2.6 45.1 2.0 Glauconite, 900°C 54.2 .5 57.1 2.1 46.6 .6 35.6 0.43 Table 2 The sorption manganese ion with modified glauconitic Sorbent Initial concentration of solution Сi.s(MnSO4), mkg/mL degree of sorption α, % Modified sample Glauconite : NaH2PO4 = 1:1 60 86.20 500 87.40 1000 89.20 Glauconite : NaH2PO4 = 2:1 60 78.30 500 80.00 1000 82.80 Glauconite : NaH2PO4 = 3:1 60 72.40 500 76.60 1000 77.70 Glauconite: NaH2PO4 = 4:1 60 27.80 500 39.3 1000 47.6 Initial glauconitic sand 60 24.3 500 26.2 1000 21.4 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org

  17. 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org Mineral Processing

  18. Maryam,T., Hossein, K., Sodeh, S., and Morteza, T, Synthesis and characterization of zeolite NaY using kaolin with different synthesis methods, Clays and Clay Minerals , vol. 62, pp 508518, 2014.

  19. Wilson, M. J., Wilson, L., and Patey, I, The influence of individual clay minerals on formation damage of reservoir sandstones: a critical review with some new insights, Clay minerals, vol. 49, pp 147164, 2014.

  20. Adriaens, R., Vandenberghe, N., and Elsen, J, Natural clay-sized glauconite in the neogene deposits of the campine basin (Belgium), Clays and clay minerals, vol.62, pp 355, 2014.

  21. Muller, F., Drits, V., Planço n, A., and Rober, T.J, Structural transformation of 2:1 dioctahedral layer silicates during dehydroxylation-rehydroxylation reactions, Clays and Clay Minerals, vol. 48, pp 572 585, 2000.

  22. Li, X ., Cai, Y.F ., Hu, X.M ., Huang, Z.C ., and Wang, J.G , Mineralogical characteristics and geological significance of Albian (Early Cretaceous) glauconite in Zanda, southwestern Tibet, China, Clay minerals, vol. 47, pp 4558, 2012.

  23. Pestitschek, B., Gier, S., and Essa, M, Effects of weathering on glauconite: evidence from the abu tartur plateau, Egypt, Clays and clay minerals, vol. 60, pp 76 88, 2012.

  24. Baldermann, A ., Warr, L.N ., Grathoff, G.H ., and Dietzel, M , The rate and mechanism of deep-sea glauconite formation at the ivory coast-ghana marginal ridge, Clays and clay minerals, vol. 61, pp 258276, 2013.

  25. Valanciene, V., Siauciunas, R., and Valancius, Z, Evaluation of glauconite rock color stability during firing, Applied clay science, vol. 99, pp 110118 , 2014.

  26. Huggett, J.M . and Cuadros, J , Glauconite formation in lacustrine/palaeosol sediments, Isle of Wight (Hampshire Basin), UK, Clay minerals, vol. 45, pp 35 49, 2010.

  27. Hassan, M. and El, S.H , Glauconitic clay of El Gidida, Egypt: evaluation and surface modification, Applied clay science, vol.27, pp 219222, 2004.

  28. Chang, S.S., Shau, Y.H., and Wang, M.K, Mineralogy and occurrence of glauconite in central Taiwan, Applied clay science, vol. 42, pp 7480, 2008.

  29. Hassan, M.S. and Baioumy, H.M, Structural and chemical alteration of glauconite under progressive acid treatment. Clays and clay minerals, vol. 54, pp 491499, 2006.

  30. Ehsan, K., Ahmad, A., Hamid, S., and Arash, A, The potential of glauconitic sandstone as a potassium fertilizer for olive plants, Archives of Agronomy and Soil Science, vol.58, pp 983993, 2012.

  31. Kuanysheva, G., Balgysheva, B., Dalabayeva, N, Preperation of low-temperature polyphosphate fertiliser by the addition of serpentine, 22nd Annual Conference, UK, p 11, 2014.

  32. Franus, M. and Bandura, L, Sorption of heavy metal ions from aqueous solution by glauconite, Fresenius environmental bulletin, 23, pp 825 839, 2014. 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org 16th International Multidisciplinary Scientific GeoConference SGEM 2016 Figure 1 and (1a ). XRD patterns of the initial glauconitic and mechanically activated glauconitic. At the bottom – dependence the degree of sorption for Mn 2+ ions mechanically activated mixtures to the concentration of the initial solution for extraction Figure 2. TG and DSC of initial glauconitic concentrate Figure 3. TG and DSC of initial glauconitic sand 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org Mineral Processing Figure 4. The scanning electron microscopy of modified glauconite 2:1 Figure 5. TG and DSC of modified glauconite 2:1 Figure 6. Changing degree of sorption of glauconitic sand for Mn2+, Cu2+, Ni2+ ions from obtained modified form of glauconitic 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org 16th International Multidisciplinary Scientific GeoConference SGEM 2016 Table 1 The contents of manganese, copper, nickel and zinc ions in the solution during the sorption with glauconitic (G) Solution and sample of glauconite Mn2+ Сu2+ Ni2+ Zn2+ Сs, mg/L α, % Сs, mg/L α, % Сs, mg/L α, % Сs, mg/L α, % Initial solution (Сis) 56.7 058.3 051.6 051.2 0 Glauconite : NaH2PO4 = 1:1 (mechanically activated) 7.8 6.2 8.4 5.6 26.4 8,9 2.6 4,9 Raw material (Glauconite) 45.1 0.4 56.5 3.0 43.9 5.0 43.5 5.0 Glauconite, 450°C 47.5 6.3 51.1 2.5 45.1 2.6 45.1 2.0 Glauconite, 900°C 54.2 .5 57.1 2.1 46.6 .6 35.6 0.43 Table 2 The sorption manganese ion with modified glauconitic Sorbent Initial concentration of solution Сi.s(MnSO4), mkg/mL degree of sorption α, % Modified sample Glauconite : NaH2PO4 = 1:1 60 86.20 500 87.40 1000 89.20 Glauconite : NaH2PO4 = 2:1 60 78.30 500 80.00 1000 82.80 Glauconite : NaH2PO4 = 3:1 60 72.40 500 76.60 1000 77.70 Glauconite: NaH2PO4 = 4:1 60 27.80 500 39.3 1000 47.6 Initial glauconitic sand 60 24.3 500 26.2 1000 21.4 16th International Multidisciplinary Scientific GeoConference SGEM2016 www.sgem.org

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