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BIO-OIL UPGRADING OVER HYDROTHERMAL CATALYSTS
Abstract
To improve the fuel characteristics, bio-oil is preceded to modernization which mainly includes hydrotreatment. This work is devoted to the study of the conversion of anisole, as one of the lignin monomers, in the presence of catalysts synthesized by the hydrothermal method. Platinum and palladium catalyst deposited on the polymer matrix of hypercrosslinked polystyrene allowed achieving about 90% of anisole conversion. It was shown that during the conversion of anisole, cyclohexane, methylcyclohexane, and phenol are the main products. The highest selectivity (approx. 64%) with respect to the phenolic compound was shown by a platinum catalyst supported on hypercrosslinked polystyrene. The palladium catalyst showed lower selectivity for phenolic compound (approx., 56%). Thus, the use of catalysts synthesized by the hydrothermal method in the processing of biomass components is a promising direction for the development of biofuel production technologies.
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Simonova V.V., Shendrika T.G., Kuznetsov B.N. Methods of Industrial Lignins Utilization, Journal of Siberian Federal University. Chemistry 4. Russia, vol. 3, p. 340-354, 2010.
Kalita P., Determination and comparison of kinetic parameters of low density biomass fuels, Journal Renewable and Sustainable Energy, USA, vol. 1, Is. 2, 12 p, 2009.
Bulushev D.A., Ross J.R.H. Catalysis for conversion of biomass to fuels via pyrolysis and gasification: A review , Catalysis Today, Netherlands, vol. 171, p. 1–13, 2011.
Bridgwater A.V., Toft A.J., Brammer J.G. A Techno-Economic Comparison of Power Production by Biomass Fast Pyrolysis with Gasification and Combustion, Renewable and Sustainable Energy Reviews, USA, vol. 6, p. 181 – 248, 2002.
Gupta R.B., Demirbas A. Gasoline, Diesel and Ethanol Biofuels from Grasses and Plants, Cambridge University Press: New York, USA, P. 140 – 157, 2010.
Oasmaa A.A., Peacocke C. Guide to Physical Property Characterisation of Biomass - Derived fast pyrolysis liquids, VTT Publications 450, Finland, p. 102, 2001.
Şenol O.I. Viljava T.-R., Krause A.O.I. Effect of sulphiding agents on the hydrodeoxygenation of aliphatic esters on sulphided catalysts, Applied Catalysis A: General, Netherlands, vol. 326, p. 236–244, 2007.
Honkela M.L., Viljava T.-R., Gutierrez A., Krause A.O.I. Hydrotreating for Bio-Oil Upgrading, in: Thermochemical Conversion of Biomass to Liquid Fuels and Chemicals, The Royal Society of Chemistry, p. 288-306, 2010.
He Zh., Wang X. Hydrodeoxygenation of model compounds and catalytic systems for pyrolysis bio-oils upgrading, Catalysis for sustainable energy, China, p. 28-52, 2012.
Elliott D.C. Historical Developments in Hydroprocessing Bio-oils, Energy & Fuels, USA, vol. 21, p. 1792 – 1815, 2007.
Roy M. J. Hydrodeoxygenation of lignin model compounds via thermal catalytic reactions, Georgia Institute of Technology, USA, p. 45, 2012.
Stepacheva A.A., Markova M.E., Bykov A.V., Sidorov A.I., Sulman M.G., Matveeva V.G., Sulman E.M., Ni Catalyst Synthesized by Hydrothermal Deposition on the Polymeric Matrix in Supercritical Deoxygenation of Fatty Acids, Reaction Kinetics, Mechanisms and Catalysis, Hungary, vol. 125, p. 213–226, 2018.
Shimanskaya E.I., Rebrov E., Filatova A.E., Matveeva V.G., Sulman M.G., Sulman A.M., Catalytic hydrogenolysis of different types of lignin obtained from sawdust softwood, Chemical Engineering Transactions, Italy, vol. 70, p. 361-366, 2018.
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