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It is rather difficult to apply thermodynamic simulation in the forecast of heavy metals migration in aquatic ecosystems due to the fact that the composition of bottom sediments in reservoirs is very changeable and uncertain. An alternative approach is proposed for solving similar problems based on the use of empirical information on heavy metal speciation in bottom sediments. This type of information can be obtained using sequential extraction scheme (for example Tessier scheme). Based on these data, effective th...

Speciation of heavy metals in bottom sediments defines their ecotoxicity and mobility and therefore needs to be studied thoroughly. Usually single and sequential extraction techniques are used to determine water-soluble, exchangeable, specifically sorbed and carbonates, bound to organic matter, bound to Fe and Mn hydroxides and residual forms. Bottom sediments of the Vyshnevolotsky reservoir (the Upper Volga, the Central region of Russia) were chosen for the research. Lithological and mineral composition of sample...