Browse

Synthesis gas for an electrochemical generator was produced in a thermochemical reactor with autothermal air conversion of methane (natural gas). Based on thermal balances of the reactor, a battery of SOFCs and a boiler-utilizer (BU) for heating primary and secondary air, cathodic air and methane, the following parameters were calculated: temperature at the anode, EMF of the fuel cell, electrical efficiency (gross) of the electrochemical generator, portion of hydrogen oxidized at the SOFC?s anode and specific cons...

Small kettle holes filled with water are commonly found objects in damp lowland landscape. Their location within an agricultural and forest area may cause, irrespective of the land use, the enrichment in biogenic substances. Deficiency of data about the phosphorus and nitrogen content in the sediments of small water bodies, which makes the discussion of this subject more difficult and restricting it only to large water reservoirs. The chemistry of the surface layer of bottom sediments (organic matter, phosphorus, ...

The stoichiometry of metal?protein complexes is pH dependent. Since mass spectrometric measurements at higher pH values are difficult in the presence of usual buffers, we extended this approach to pH in excess of 10 by adding ethanolamine to the electrospray solution being investigated. Therefore, a new method for probing the metal ion-peptide complexes at high pH utilizing electrospray ionization mass spectrometry (ESI-MS) has been advanced. Nevertheless, the high pH ESI-MS spectra of peptides are far too complex...

The stoichiometry of metal?protein complexes is pH dependent. Since mass spectrometric measurements at higher pH values are difficult in the presence of usual buffers, we extended this approach to pH in excess of 10 by adding ethanolamine to the electrospray solution being investigated. Therefore, a new method for probing the metal ion-peptide complexes at high pH utilizing electrospray ionization mass spectrometry (ESI-MS) has been advanced. Nevertheless, the high pH ESI-MS spectra of peptides are far too complex...