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Organic matter of lignites from five Tertiary deposits in the Czech Republic was studied and the general goal was to characterize a series of different coal lithotypes in relation to depositional environment from the viewpoint of organic petrology and geochemistry. Coal samples were chosen to cover various lithotypes: xylite rich coals, matrix coals, liptobioliths, and sapropelic coals. The samples differ in ash, sulphur, carbon, hydrogen, oxygen and volatile matter contents, and calorific values. Xylite rich and ...