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To better investigate the effect of additives on the hydrate phase behavior and to enrich the hydrate phase equilibrium data in the presence of metal compounds. Hydrate experiments were carried out in the existence of a pure quartz porous medium impregnated with a metallic powder made of 200 g FeSi3, Inconel 718 and CuSn12 alloy, respectively. Results were obtained the entire process of methane and carbon dioxide hydrate formation and decomposition in all cases. In this 949 cm3 lab-scale reactor, metallic powders ...

This article describes gas hydrates formation, with methane and carbon dioxide as guest compounds, in a small-scale experimental apparatus, appositely designed to reproduce marine offshore reservoirs. The sediment consisted of pure quartz porous sand impregnated with FeSi3 particles, which are produced via gas-atomization and are usually destined to applications in additive manufacturing. Experimental results were compared with the theoretical equilibrium conditions for both types of hydrates. It was established t...

The gas hydrate formation is a non-stoichiometric process, which may be affected by a great number of variables, rather than thermodynamic conditions. Several chemical additives were found to act as inhibitors or promoters (or both together under specific situations) for gas hydrate. The most known chemical inhibitor is sodium chloride, whose effects needs to be widely investigated, due to its presence in about 97% of discovered hydrate reservoirs. However, other elements may intervene on the formation process and...