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Metal?microbe redox interactions have implications for ore formation and recovery of uranium from ore-containing materials. The speciation of uranium in relation to its bio-availability is reviewed. U(VI) is the major form of U in oxic surface waters, while U(IV) - in anoxic waters. The ability of uranium to bind the bacterial cell surface is dependent on its physicochemical form. Within solid-phase organic matter, microbes can influence oxidation state and stability of uranium through direct enzymatic reduction, ...