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Polyoxometalates (POMs) are discrete, anionic metal-oxygen clusters of early d bloc metal ions in high oxidation status (e.g. MoVI, WVI) with a very large structural and compositional variety, leading to interest in many different areas (catalysts in homogeneous and heterogeneous catalytic oxidation of organic compounds or biochemical reactions, activity in enzymatic redox processes, as antitumoral, antibacterial and antiviral treatments etc). An important subclass of POMs is the {XMo6O24} structure type, Anderson...