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Based on the example of arsenic, co-occurring in the Cu-Ag deposits (the Fore-Sudetic Monocline, Poland) while considered to be harmful for the environment, the paper describes difficulties associated with the reliable estimation of trace and rare elements concentrating in parts of deposits. The characteristics of these elements that make the estimation of the resources difficult include: extremely high variability of content, the dominant share of random components in the differentiation structure, and the concep...