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The mechanism for the selective adsorption of zirconium ions in a highly acidic medium by sodium-modified titanium dioxide was proposed. The mechanism of adsorption of zirconium ions in an acidic medium by this adsorbent is similar to the mechanism of adsorption of strontium ions in a neutral medium. The selectivity of Na-TiO2 is due to the positively charged surface of the adsorbent in the highly acidic medium.

The main features of the measurement of the trace amount of 90Sr using ICP-MS inecology and nuclear forensics were established. Among them are sample-specific matrixeffects which may enhance or suppress the analyte signal, spectroscopic interferences,poly-ions formation, isobaric interferences, and reagent contaminations. Proposedsolutions to these problems: external and internal calibration of mass-spectrometer, precleaning and pre-treatment of the adsorbents and reagents, as well as selective removingisobar inte...