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Today, supply of hydrogen in processes of hydrotreating of heavy hydrocarbonic raw materials is one of the main expenses in the course of hydrocracking. Therefore, alternative modernization processes that do not use externally supplied hydrogen are desirable and necessary. This scientific work is devoted to solving the problem associated with the processing of high-viscosity oils and shale hydrocarbons in supercritical water to valuable petrochemical raw materials with a high ratio of hydrogen to carbon. The catal...

The work is dedicated to solving a scientific problem related to the effective use of steam-thermal methods for extracting hard-to-recover hydrocarbon resources from carbonate reservoir rocks using catalytically active metal compounds of variable valency. The work is aimed at studying the behavior of nanoheterogeneous catalysts based on Al, Ni, Mn compounds on an organic matter in the presence of a carbonate rock under conditions of steam heating effect. The experimental part of the project was carried out on a la...

This paper presents the results of the study of Kraft lignin hydrogenolysis process, using 5%Pd/C. The catalyst was investigated using the following physico-chemical methods: X-ray photoelectron spectroscopy, infrared spectroscopy of diffuse reflection of the adsorption of CO (DRIEFT), transmission electron microscopy, thermal gravimetric analysis, differential scanning calorimetry, the low-temperature nitrogen adsorption. Among the products obtained during hydrogenolysis of lignin the most promising for fuels are...

The study of the rate of autoregeneration of soil microbial community allows developing the strategy of soil management. The activity of cellulase in soils shows the rate of biological transformation of plant residues and may be used as indicator of autoregeneration of soil microbial community in disturbed soils. The most reliable data on the activity of cellulase in soils can be obtained with the help of the application method, which is based on a reduction in the mass of cellulose fiber that has been incubated i...

The proposed paper analyzes an investment project implemented to create a complete, efficient, simple and sustainable Community waste management system for a number of settlements in the western part of Romania. The purpose of these actions is to create a functional intervention framework of the local public administration authorities in the field of environmental protection in the target area. The implementation of the system proposed by this project will lead to compliance with current environmental rules and le...

The iron phosphates coagulant is commonly used in lake restoration to improve water quality and eliminate cyanobacteria bloom. Nevertheless, the short-term abiotic environment transformation in particular inside macrophytes communities is still not sufficiently studied. The field experiments were carried out in mesocosms installed in Chara hispida community. This species is characteristic for eutrophic lakes, therefore is strongly vulnerable to restoration treatments. In the study five parameters were analysed: pH...

Energy policy of the European Union aims to move towards the sustainable and green energetics, therefore, identification and exploitation of renewable energy resources is of high importance in all EU member states. One of the types of renewable energy production is cogeneration of heat and power from biomass. Cogeneration becomes more and more topical in the Baltic States as various kinds of biomass, e.g., forestry and agriculture residues, cultivated plants for biomass are rather easy obtainable. For example, in ...

It is well-known that earthquakes do not consider boundaries and Bulgaria is also subjected to seismic impacts from earthquake sources located in the neighbouring countries, i.e. outside its territory. Without doubt the actual impact from these sources on our built environment is to be taken into account by our engineers and planners. This could be done properly if only based on instrumental records of real events and after assessment of their characteristics. The effect of Vrancea quakes on our territory is rathe...

The cementing of wellbores is of the utmost importance at each stage of the drilling jobs. Regardless the conditions in the well, the aim of the cementing job is to efficiently seal the annular space between the casing and the wellbore wall, and to liquidate absorptive zones and also the flow of fluids in the annulus. The properly performed cementing job guarantees successful and safe exploitation of the well. A correctly performed cementing job in a borehole depends on the design of the borehole, geologic-reservo...

Nowadays, issues related to intellectual capital, its valuation and management are becoming a significant strategic problem. The nature of the modern market excludes practically the possibility of completely omitting this element in management processes. Building market advantage requires more and more intensive recourse to intangible assets. Traditional forms of doing business in many areas do not bring the expected results. The main problem associated with intellectual capital hindering its wider application in ...

The discovery of Bakyrchik gold-sulfide black shale deposit was in 1953. It is situated in Western Kalba metallogenic zone, originated in late Paleozoic age as a separated line between palaeocontinents of Kazakhstan and Altai-Mongol. The Bakyrchik deposit has acicular arsenopyrite and arsenical pyrite containing micron-size (2-5 ?m) gold inclusions. It is large gold reserve (280 tons) in black shales of northern east Kazakhstan. The gold is associated with acicular arsenopyrite, lesser extent of pyrite. The sulfid...

The use of biomass as a renewable fuel for production of heat and electricity is regarded as a key to reduce fossil fuel dependency, and thereby to reduce net CO2 emissions. Fluidized bed (FB) technology is widely accepted as the most energy efficient process for thermal conversion of biomass. One of the often-mentioned drawbacks is the building up of agglomerates within the process because of bed material-ash interaction. To avoid unplanned operational stops due to agglomeration, bed material is continuously repl...

According to FAO, the Food and Agriculture Organization of the United Nations, global annual charcoal production amounts to 52 million metric tons. Around half of the population in South America depends on forest-sourced resources (firewood, charcoal) to cover their basic energy needs, and in some countries large-scale industrial charcoal usage is further common, e.g. in Brazil in the production of pig iron for steel. To limit adverse impacts on forest health, sustainability of charcoal production merits high atte...

New Russian Integrated Pollution Prevention and Control (IPPC) legislation has come into forth at the beginning of 2018. In 2015-2017, 51 Information and Technical Reference Books on Best Available Techniques (BREFs) had been developed and officially approved. About 6,500 installations of various sectors had been registered as IPPC (or Category I) installations. In 2019-2025, all of them will be obliged to demonstrate compliance with requirements of Best Available Techniques (BATs) set by respective sector BREFs a...

Gas hydrates have been represented as a promise technology for many of applications, as gas mixtures separation, CO2 capture, transportation, and sequestration, transport and storage of methane, and seawater desalination. Reduction of onset temperature/time for hydrate formation and increasing the hydrate growth rate are very critical for these applications. In this study for the first time we want to introduce the application of gelatin as a cheap, biodegradable, sustainable and effective promoter for methane hyd...

Global issues such as resource scarcity, climate change, land and ocean pollution linked to the widespread growth model of production and consumption have led to the introduction of many concepts and approaches such as 'sustainable development' and 'green growth', and etc. It is also a circular economy, and it has many similarities to these concepts and approaches that deal with the relationship between people and their environment. However, it has distinctive use and, in principle, has more radical consequences t...

The paper deals with burning processes, combustible materials and materials. Each fire is accompanied by combustion processes that depend on combustion conditions, in particular the presence of flammable substances and materials, oxidant and source of initiation. Fire is burning spreading uncontrollably in time and space. Fever represents a set of exothermic physicochemical events, in which the redox reactions occurring in the release of a considerable amount of thermal and light energy, at the same time release f...

It is well documented that the interlayer space of clay minerals, notably smectites (e.g., montmorillonite), can be intercalated with wide variety of inorganic cations or organic cations through ion exchange reactions or using other physical and chemical means of interaction. When the modification of smectite is performed with organic cations, their properties change from hydrophilic to hydrophobic. Therefore, the resulting materials become efficient sorbents of organic contaminants in wastewater, e.g., as sorbing...

Carbon capture storage (CCS) technology is expected to help reduce the anthropogenic carbon dioxide emissions, however, application requires finding the rock formations with sufficiently large storage capacities. Water-bearing formation allow to store a high-volume CO2. Nevertheless, the assessment of the capacity of aquifers structures remains a problem. In this work reservoir simulation was developed to estimate CO2-storage capacity because it allowed to take into account the effect of heterogeneity in an aquife...

The effect of coke formation on the pore structure and permeability in the process of the in-situ upgrading of heavy oil under supercritical condition has attracted more and more attention. Studying coke formation induced by thermal treatment is currently an important task for selecting the optimum upgrading technologies for heavy and extra-heavy oils. This research is intended to evaluate coke formation through the process of aquathermolysis in the condition of superheated steam injection. In this study, upgradin...

The investigated cold spring (10.4-10.9 ?C) is located onto a reverse fault zone within the Subcarpathian nappe (Vrancea region). A small travertine deposit has precipitated along the stream. The spring-water samples display an essentially calcium-bicarbonate chemical facies, indicative of a prevalently meteoric water contribution. Still significant Na and Cl concentrations - each of them amounting, when expressed as miliequivalents, to about one third of the HCO3 concentration - also suggest mixing with a signifi...

Production of electricity in power plants using steam-driven turbines represents today and will continue to remain for decades the main source of such energy, regardless of the fuel consumption type: fossil or nuclear. Even some types of power plants using renewable energy, such as solar energy, transform it first into steam energy. Considering that nowadays about 80% of total world electrical energy is produced by power plants that use steam energy, it is very important that the efficiency and reliability of esse...

Cogeneration, or combined heat and power production (CHP), delivers both electricity and heat simultaneously, which achieves high overall energy efficiency. Although CHP technologies are state of the art, and advantages of their adoption are well known, 70% (European Union) to 80% (worldwide) of the existing potential remains untapped. Initiatives fostering more widespread uptake of cogeneration so far often focus on large scale electricity supply schemes combined with the operation of district heating, while the ...

One of the possible solutions to reduce or eliminate landfill gas emissions is to cover the landfill with bioactive cover layer, where methane is oxidized in-situ. The main innovation of the closure project at Kudjape landfill, Estonia, was to extract the < 40 mm fine fraction from the same landfill cell by using landfill mining technology in order to construct a methane degradation cover and to restore the previous landfill area for the benefit of the community. European larch (Larix decidua) and Norway spruce (P...

The present study explores the impact of natural and climatic factors on the conditions and efficiency of the activities of Russian public utility companies in the context of the theory of the economic system's adaptation to the rapid changes occurring in the natural and climatic conditions using the example of the Far North. Given the change and uncertainty in the factors of the external and internal environment for public utility companies, innovative processes in the field of management are regarded as an imman...

Agricultural production as a share of gross domestic product in Latvia in the year 2016 was 3.2%, which was 1.5% more than in 2015. In 2016, the sown area of cereals amounted to 716.0 thousand hectares, which was about 43.6 thousand hectares or 6.3% more than in 2015 [1]. This indicates the development of the agricultural sector, which will require production resources, as well as appropriate technology machinery to be available. The agricultural sector has to be seen in the context of rural development, where the...

Due to the fact that the printing industry is one of the largest production departments in the EU, its impact on the environment cannot be neglected. The printing activity is based on the use of appropriate substances and chemical preparations. They occur mainly at the stage of preparing printing material and subsequent printing. Chemical and photochemical processes occurring during printing, the use of water and air for cooling machines and devices as well as production wastes - these are factors that may affect ...

The research is focused on the elemental composition of humic acids (HAs) extracted from sapropel found in lakes of the Middle Priobye and the southern Ob-Irtysh basin of West Siberia. Particular attention is given to the fact that sapropel samples were formed under various hydrothermal and environmental conditions. The peculiar features of HA elemental composition, which are evident in element content, atomic ratio and oxidation degree, were revealed. They indicate the relationship between aromatic and aliphatic ...

The Verkhoyansk fold-and-thrust belt (VFTB), composed of terrigenous-carbonate rocks of the Upper Proterozoic, Paleozoic and Mesozoic age and formed in the Late Mesozoic time, stretches along the north-eastern and eastern framing of the Siberian platform. Studies were carried out (from south to north) in the Kuranakh and Kharaulakh segments of the Western-Verkhoyansk sector of VFTB and in the Olenek sector of VFTB. Structures of the Kuranakh and Kharaulakh segments have submeridional strike, and the Olenek ? subla...

The breeding value of the selection candidates is the criterion on which the best individuals are retained for breeding, corresponding to proportion of the selected individuals. When the livestock is grown in an ecological system, the only leverage by which meat production can be increased is the use of the individuals with the highest genetic merit. The average of breeding values of selected individuals coincides with genetic progression on generation, implicitly with the growing production in the considered trai...

One of the most important problems in the socio-economic development of the adjacent territories of Russia, China and Mongolia is water supply. Russian regions, including the Republic of Buryatia, the Trans-Baikal Territory and the Amur Region, are characterized by sufficient reserves of water resources, relatively evenly distributed over the territory. The structure of water use in the regions is dominated by energy and also in the Trans-Baikal Territory and the Amur Region large volumes of water consumption are ...

The buildings and services sector accounts for about 40% of total EU energy consumption, in particular residential heating accounting for 78% of this consumption. Increasing the energy performances of buildings, together with the effort to mitigate greenhouse gas emissions and, implicitly, climate change are the main directions of intervention of worldwide energy strategies. In the context of a process of global energy transition, Romania - as a member of the European Union, also is engaged in a policy of changing...

The quality of water sources used for drinking water production is highly varied. Many problems arise in groundwater due to the content of hydrogen sulfide and ammonia. Thei presence of its in water affects the organoleptic properties, in disosolved form the hydrogen sulphide confering undesirable taste and irritating rotten egg smell which make it unpalatable. Ingestion of sulphides through drinking water can result in stomach discomfort, nausea and vomiting. Ammonia in concentration above 1.5 mg/L can cause odou...

Biomass is one of the most promising renewable energy sources that could contribute to sustainable energy supply including the reduction of greenhouse gas emissions. Russia has a huge potential for producing biofuel from wood raw materials. However, forest bioenergy is now at the first steps of development. In this regard, the problem of effective choice of the suitable wood fuel supply chain is very significant. A toolset of decision support systems for wood harvesting and forest bioenergy logistics has been deve...

In the current work, a series of poly(sodium acrylate)-co-acrylamide (polyNaA-co-AAm/pectin and polyNaA-co-AAm/bentonite) superabsorbent composites were prepared using pectin, bentonite, acrylamide and acrylic acid (AA) in the presence of N,N-methylenebisacrylamide (MBAAm) as cross-linker and a mixture of ammonium persulfate and TEMED as initiator. The structure and sorption capacity of the developed composites were characterized by Fourier transform infrared spectroscopy (FTIR), voltammetry and UV-visible spectro...

The analysis of bottom sediment quality is an important yet sensitive issue. The anthropological influences (i.e., urban, industrial and agricultural activities) as well as the natural processes (i.e., changes in precipitation amounts, erosion and weathering of crustal materials) degrade surface water quality and impair its use for drinking, industrial, agricultural, recreational and other purposes. Due to spatial and temporal variations in water chemistry, a monitoring program that provides a representative and r...

At present, biotesting methods are widely used to assess the toxicity of environmental objects. Priority environmental pollutants include heavy metals and phenolic compounds. The aim of this work is to compare the sensitivity of biotesting methods to determine the toxicity of waters containing heavy metals and phenolic compounds. To achieve this, biotesting methods based on the survival of Daphnia magna crustaceans, changes in the intensity of bioluminescence of the saccharifying bacteria (the "Ecolum" test system...

Climate reconstruction in the Holocene for the Russian Central Chernozemic region with use of palynological and soil research of deep cores in floodplain deposits and archaeological monuments are carried out. In the Preboreal period area was covered by meadow and grass steppes, pine and birch forests were locally spread. In the Boreal period they were dominated, broadleaved species were noted in small content at its beginning, in its middle span oak and hazel appeared, in the final phase ash and maple added. In th...

Complex of researches (chemical, mineralogical, X-ray phase, rare-earth, isotopic analyses) of volcanogenic-sedimentary rocks, composing basal horizon of the Osipayskaya formation of the Carnian stage in the middle course of Lena river ((Bulkur anticline) (Grakhanov, Smelov 2010, Proskurin et al, 2012), where diamonds of V and Vii variety according to L.Y. Orlov classification, was performed. Granite, ilmenite, spinellide, rutile are identified in rocks among minerals of heavy fraction. According to X-ray phase an...

In the case of the close location of various engineering structures to the place of drilling and blasting operations for ensuring the preservation of these structures there is a necessity of the accurate forecast of the level of possible seismic effects. The amplitude of seismic vibrations is influenced by many factors that are not considered in the regulatory method of determining seismically safe distances. Therefore, the only reliable approach to an accurate prediction is the direct instrumental measurements. T...

The purpose of the research is determination and comparison of the porosity values of the whole core obtained by nuclear magnetic resonance (NMR) and X-ray computed tomography (CT) methods. To achieve the purpose of the research, it was necessary to solve the following tasks: a) measurement of porosity of a whole core by NMR; b) obtaining core porosity values using X-ray CT; c) comparison of the obtained values, explanation of the differences in the porosity using these two methods; d) proposal of new approaches i...

The article describes the newly diagnosed incidence of the musculoskeletal system in the regions of the Republic of Kazakhstan (East Kazakhstan region) with the identification of risk levels, mapping, correlation of environmental factors and clinical and laboratory data on osteopenia diagnostics with the Omnisense-7000. A high incidence rate was detected in the Borodulikha district, close to the former Semipalatinsk nuclear test site and in the industrial city of Ridder, the center of the mining and metallurgical ...

Flow lines are one of the key elements of oil field facilities as they ensure safe transport of raw multiphase mixtures of gas, oil and water from reservoir to reception facilities. The growth of oil extraction in Russia makes the issue of developing new deposits and maintaining high production of oil and gas from existing ones particularly important. Therefore, maintenance of flow lines in service is of great significance. Most of Russia?s oil production originates in West Siberia . The territory is characterized...

Small kettle holes filled with water are commonly found objects in damp lowland landscape. Their location within an agricultural and forest area may cause, irrespective of the land use, the enrichment in biogenic substances. Deficiency of data about the phosphorus and nitrogen content in the sediments of small water bodies, which makes the discussion of this subject more difficult and restricting it only to large water reservoirs. The chemistry of the surface layer of bottom sediments (organic matter, phosphorus, ...

A comprehensive, three-year (2013 ? 2015) geochemical analysis of soils has been conducted within impact areas of the main Russian and Norwegian coal mining centers in Svalbard. This study was focused on identifying both natural and technogenic trace elements and rare earth elements within a variety of landscapes with location of emission sources and natural factors of contaminants' distribution having been taken into account. The concentrations of macro, micro elements, Trace Elements (TM) and Rare Earth Elements...

Establishing of pore fluids pressure is one of the critical challenges encountered in the formations opening in drilling. Pores fluids pressure evaluation through geophysical methods involves live recordings of the collector parameters using LWD (Logging While Drilling)/MWD (Measurements While Drilling) techniques. Empirical relationships of the dependence of pore pressure and the measured parameters use exponents whose values are accepted as constant. These exponents were determined on the basis of experimental d...

Geological storage of CO2 provides a way of reducing CO2 emissions into the atmosphere, by capturing CO2 from major industrial CO2 sources, transporting and injecting it into suitable deep brine aquifer rock formations. The selection of the potential site for the CO2 storage is based on the analyses of all the available geological and geophysical data (well data, seismic lines, gravimetric and magnetic maps, outcrops, geological cross sections, pressure and geothermal regimes, mechanical rock proprieties, chemical...

In case of using equipment in areas classified as with hazard of potentially explosive atmospheres, this shall be designed so as to avoid the ignition of the surrounding explosive atmosphere in which it is intended to operate. Equipment designed for use in potentially explosive atmospheres have to be assessed according the provisions of the ATEX Directive 2014/34/EU regarding the ensuring of explosion protection characteristics. In case of electrical equipment this assessment usually uses the provisions of some sp...

Constructive details of welded steel industrial structures involve critical areas in the structure. A welded steel structure behaves differently toward a steel structure made of laminated steel profiles in a pervasive corrosive environment. Details of the joining of the steel elements must correspond primarily to the strength of the welded steel structure but also to the impact of the corrosive environment, that is to say, some details must be chosen to fade the effect of the corrosive environment. The paper will ...

The reliable determination of solid material thermal properties (thermal conductivity, thermal diffusivity and heat capacity) are significant for various industries. Knowledge of thermophysical characteristics of reservoir rocks is essential in developing high viscous oil deposits by thermal methods. One of the biggest problems in experimental investigation of thermophysical properties concerns with measurement errors due to multidimensional character of thermal flow (generally, in most cases, one-dimensional theo...