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Mesoporous solids include metal oxides, silica, phosphates and other materials. They may contain various acidic and basic sites which are, in combination with metal nanoparticles, metal atoms, functional groups, etc., could be efficient multifunctional catalysts for cascade reactions. In this shot review, the most important aspects of such catalysts that furnish their catalytic activity and selectivity for cascade reactions in biomass processing discussed. A combination of one metal with another or with metal oxid...

This work is aimed at the search of optimal conditions of selective hydrogenation of 2-methyl-3-butyn-2-ol (MBY) to 2-methyl-3-buten-2-ol (MBE). The main question was if the common slurry reactors are suitable for this reaction under ambient hydrogen pressure with the use of environmentally friendly solvents. Thus, we investigated the effect of the reactor type (shaker-type or slurry), temperature and solvent nature (isopropanol, n-butanol or toluene were used) on the behavior of a palladium catalysts (1 wt.% of P...

Levulinic acid (LA) obtained by processing of plant biomass is used to synthesize many important compounds, among which is gamma-valerolactone (GVL) - a platform chemical. At present, bifunctional catalysts based on inorganic supports are the most widespread in the reaction of selective hydrogenation of LA to GVL. Polymers can serve as promising alternative to inorganic supports. In the framework of the presented study, the series of amorphous aromatic polymers was synthesized using different monomers: phenanthren...

A series of platinum catalytic systems stabilized in aromatic polymers were obtained in this work. Commercially available styrene-divinylbenzene (MN100) and polymers synthesized by one-stage crosslinking by the Friedel-Crafts reaction from benzene, naphthalene, and an equimolar benzene-naphthalene mixture were used as polymers. The obtained systems were tested in liquid-phase hydrogenation reactions of benzene, toluene, and benzene-toluene mixture, as well as anthracene in a dodecane medium. The reaction products ...

The scale of annual reproduction of cellulose-containing biomass in nature allows us to draw an unambiguous conclusion that cellulose is the only source of raw materials for the chemical and fuel industries, representing a real alternative to fossil resources and, first of all, oil. Cellulose is the main component of plant biomass. According to some estimates, almost half of the organic carbon in the biosphere is contained in cellulose. Hydrolytic hydrogenation is a special case of carbohydrate hydrogenation. With...

This paper presents the results of a study of the hydrolysis of microcrystalline cellulose in a subcritical water medium. The influence of temperature, time, cellulose/water ratio, cellulose particle size, and other parameters on the hydrolysis process was studied. The influence on the process of pretreatment of aqueous dispersions of cellulose with ultrasound was studied. It was shown that the optimal processing time is 30 min (~ 150 kJ). Over a given period of time, destruction and partial hydrolysis of the amor...