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The problem of recycling worn car tires is ecologically and economically important. Worn-off tires are a source of long-term environmental pollution. Tires subject to no biological decomposition, they are inflammable and being ignited 1 ton of tires releases in the atmosphere 270 kg of carbon black and 45 kg of toxic gases. At the same time, they contain valuable raw materials such as rubber resin and metal. The most optimum of all known tire-recycling methods is low-temperature pyrolysis that provides complete re...

Water is the key Element in social and economic development of the country, which is becoming a scares resource due to over-increasing demands of the growing population, Agriculture, Hydropower and Industrial Users. Site selection of industries in the river side, usually affect on the monitoring program. Thus the monitoring of the rivers for the effective management and planning in the water section has become most predominant aspect and need to pay attention to the best program for industries location. Haraz is a...

Gold mining is attracting increasing attention in many countries of the world, although it has a major impact on the environment. Large quantities of hazardous chemicals such as mercury or sodium cyanide are consumed to recover gold from its ores. Therefore, this activity should be carefully regulated by means of global directives based on an up-to-date knowledge of ecotoxicity principles and modern environmental standards. In light of recent developments in world gold mining, Turkiye has caught the attention of f...

The analysis of the practical applications of the findings of the preliminary tests for the effectiveness of the disinfection treatments with high-frequency cold plasma conducted on samples collected from patrimony items and reference materials of organic nature has shown that the microbiological investigations confirm the biocide action of the HF plasma in fighting bacteria (after 45 minutes in the samples of icon wood and natural silk, 60 minutes in the cotton samples, 90 minutes in the archaeological wood and l...

This report describes the morphogenesis of the cyathium in two subspecies of Euphorbia myrsinites L. occurring in the flora of Romania related to the vascular transition. Our histo-anatomical researches established the origin of the vascular system in the different parts of the cyathium (involucre, nectary glands, monostaminate male flowers and female flower).

Our investigations have focused on observations concerning the horse-chesnut’s (Aesculus hippocastanum L.) leaves in various phenophases, the state of the leaf surfaces and histo-anatomical changes of the leaves under the influence of the atmosphere pollutants (sulphur dioxide, chlorine, ammoniac, lime or cement powders). The histo-anatomical changes induced by the gaseous and solid atmosphere pollutants on the lamina have been observed in protecting tissues, assimilator tissues (the palisade and the spongy tiss...

In this paper it has been assessed the current situation of the old vestige material deposits created during the Pb-Zn concentrate production process. Flotations of Stant\"erg, Kishnica and Albanik, have exposed those vestige materials in the open surface field and are treated as main source of the air contamination in Mitrovica and surroundings, Kizhnica and Albanik. The results which make powerful the opinion that application of the hydro filling method of exploitation in all Trepca mines are shown as well, sinc...

The photodegradation of Acid Yellow 23 a model compound from monoazo textile dyes was investigated using TiO2, SnO2 and TiO2+SnO2 suspension as photocatalysts at different gap sizes. The results showed that the coupled particles were not much different from single TiO2 system at the gap size of 4.5 cm in a batch reactor. But the coupled system was more effective when the gap size was reduced to 2.5 cm. A complete decolorization occurs at the gap size of 1.1 cm after 20 min of irradiation while 90\% decolorization ...

Prospecting and exploration activities for oil and gas in a number of cases are connected with some environmental impacts in the location of their implementation. Depending on the applied prospecting and exploration methods – geophysical or drilling methods or combination of both - the environmental impacts comprise mainly of: air emissions from the equipment engines, short-term damages to land and soil, contamination of surface and ground water, waste generation, cuttings in forests, etc. The implemented comple...

INTRODUCTION Within the scope of the recently started initiative SAFEMANMIN under 6th Framework Programme, a preliminary report about methods used for the characterization of mining wastes in several Eli countries (Austria, Italy, Greece, Poland, Norway, Spain, France, Germany, Bulgaria and Romania) has been complied. This study is based on the Reference Document on Best Available Techniques of Tailings and Waste-Rocks in Mining Activities, prepared by the IPPC Office in Seville (July 2004). It aims on establishin...

Extraction of vanadium, nickel and iron contained in spent catalyst coming from the manufacture of sulfuric acid (main elemental composition: 3.5\% V; 0.63\% Ni and 7.9\% Fe) was studied. The effects of roasting and leaching temperature, concentration of the leaching reagent, reaction time and pulp density on the extraction of vanadium, nickel and iron were determined. Sulfuric acid was used as leaching reagent. ANOVA was used to find out the optimal leaching conditions and to analyze the results. The results obta...

It’s explored and analyzed experience for treating of building refuse’s at the world in cities with over 500000 populations. It’s collected and systematized dates for existing quantities of building refuse’s for last 3 years at the area of Sofia city. There are shown a technological process and choosing a machine group for rehabilitation of building refuse’s. There are made economical analyze for competitive power between rehabilitation and store in depot.

Recently, the effect of noise pollution appeared due to noise increasing from highway transportation, especially, the great majorities of the people living in city centers. Identifying the noise levels have gained great importance in terms of planning of the cities, regions, industries and our being informed how degree the noisy pollution have influenced our daily life. Development plans performed in our country have been carried out without taking into consideration the factor of noise pollution. One of the bigge...

Most of the coastal zones in Europe are under the high level of anthropogenic pressure. Intensive use can lead to a devaluation of the natural capital of these zones and negatively affect the social and economic balance. These issues cannot be solved by the South-Eastern Baltic Region States separately (e.g. common natural and cultural heritage, transfers of pollutants and sediments, tourist flows, maritime safety) and requires international collaboration. One of the ways to ensure sustainable development of the c...

In our paper, the investigations have focused on observations regarding the physiological and biochemical changes on the horse-chesnut’s (Aesculus hippocastanum L.) leaves during their ontogenetic cycle under the influence of the atmosphere pollutants (sulphur dioxide, chlorine, ammoniac, lime or cement powders). The foliar chlorosis and necrosis represent the clear manifestation of deep physiological modifications, as well as severe structural alterations, which affect the average content of water, dry matter, ...

The increasing use of paste backfill in underground mining makes it necessary to quantify the effect of tailings properties, such as physical and chemical properties, on the performance properties of cemented paste backfill (CPB). The mechanical performance of CPB placed in underground openings (i.e. mine stopes) is often different from the one predicted in laboratory studies even under similar curing conditions of temperature and humidity. This observation is presumably due to the specific consolidation and drain...

The earthquake jeopardy for our country is a reality that can not be ignored, since 98\% of Bulgarian territory is an earthquake-prone area. Among all natural disasters, earthquakes are the greatest contemporary menace - according to UN statistics. Hence, the existence of appropriate resources for effective earthquake protection is the relevant background for the sustainable economic development of any modern state. The continuous seismic monitoring of strong earthquakes, affecting the territory of Bulgaria is car...

Companies decide to implement an EMS for a variety of reasons, and choose the type of EMS that corresponds to their needs, aspirations, and capacities. In doing so, they need to think about the ways in which they wish to imbed their EMS within overall corporate strategies and how to link it with other management support tools that they have in place. If an EMS is not supported by appropriate corporate governance is unlikely to have an efficient impact. For example, the responsibility for corporate environmental po...

We report in this paper the preliminary results obtained during removal of pesticides from industrial wastewater by Fenton’s reagent. Fenton process is attractive alternative to conventional oxidation processes in effluent treatment of recalcitrant compounds. The aim of this study is to evaluate the efficiency of fenton process for the reduction of COD in wastewaters from pesticide industry. Several parameters were also studied: dose of Fe+2 and H2O2. The process of pesticide removal from industrial wastewater u...

The present work aims at presenting the main research topics of GPhI in the field of numerical air pollution modeling. The basic dynamic and pollution transport models, applied for the purpose are briefly described. Some study results are demonstrated, concerning air pollution modeling in local and regional scales.

The quantity and the content of the landfill gas, emitted/extracted from landfill for non-hazardous waste “Suhodol” have been studied. Modeling calculations have been executed and forecast data for the quantity of the emitted and utilized landfill gas for the period till 2040 have been done. Methods for the treatment of the landfill gas, as it consists of methane - a powerful greenhouse gas, have been presented. The applicability of the presented different methods for Landfill “Suhodol” has been assessed. ...

TOC (Total Organic Carbon), TKN (Total Kjedhal Nitrojen), tP (total Phosporus), C/N (Carbon/Nitrogen ratio) contents and other properties of Municipal Solid Waste, in Д°stanbul are suitable for Compost Production. Compost is an extremely useful agent in agriculture, provides humous to soil, improves its porosity, workability, aeration and needless to say improves water absorption capacity. It also helps increasing the number of saprofit micro organisms and helps plants to get more of fertilizers. Another advantage...

We have studied 15 species of ligneous plants angyosperms, spontaneous and cultivated ones – in areas adjacent to industrial platforms: Borzeşti (Bacău county), Bicaz and Taşca (Neamţ county) - Romania; in the first case, the noxious substances are mainly gaseous (sulphur dioxide, chlorine, ammoniac), but also solid (carbon black, soot); in the other two cases, the noxious substances are mainly solid ones (lime or cement powders prone to sedimentation). Our investigations have focused on observations concern...

Ore dressing leads to producing of great quantities of waste which are stored in special waste depositories (tailing ponds). They occupy large areas and their exploitation provokes air, water and soil contamination of the surrounding territories. Reclamation is one of the most radical methods for recovery of the environmental components, creation of conditions for grass and forest growth and formation of appropriate landscape. The current study aims to determine the anthropogenic impacts on the soils in the region...

Plant growth-promoting rhizobacteria (PGPR) can effect plant growth and development in two different ways: indirectly or directly. Indirect promotion of plant growth occurs when these bacteria decrease or prevent some of the deleterious effects of phytopathogenic microorganism. The most important way is the direct way, when bacteria promote plant growth by providing the plant with a compound that is synthesized by the bacteria from plant rhizosphere. From this point of view there are many studies that show the imp...

For identification, preliminary selection and mapping of potential sites for regional waste landfills methods are applied, which are based on modern technologies - remote sensing, automated procedures in GIS environment for reduction of selected potential sites on the basis of pre-set categories and criteria as well as computer-aided visual interpretation of vector and raster data from the “CORINE Land Cover 2000 - Bulgaria” project. Office activities are followed by field investigations during which the main ...

The selective bio-solubilization of mineral sulphide deposits has had an upward development lately due to the irreversible depletion of the ore deposits and the accumulation of large quantities of refuse dumps, the process being equally important for the economy and the environment. This paper aims at carrying out a quantitative assay of both the heterotrophic and the sulphur-oxidising bacteria of the Thiobacillus genus found in samples of mine waters collected from the Barza and Valea Morii mining sites in the Ap...

We present a method for the neutralisation of heavy metals – Pb, Zn, Cd and Cr in contaminated water and soils by binding them into water-insoluble complexes, inabsorbable by plants, which was found to be effective under laboratory and green-house conditions. By introducing multiblock copolyethers (MBPE) and low molecular weight organic chelates (LOC) in water, containing heavy metal ions, they interact stoichiometrically and precipitate, affording water of irrigation quality. Treatment with MBPE and LOC (by sin...

Laboratory investigations on zinc ions removal from model solution in a column with fixed bed zeolite clinoptilolite were conducted. Experimental dynamic curves for sorption depending on the bed height of zeolite and velocity of treated solution were received. The main constant parameters characterizing the process at breakthrough were defined. It was established that the bed column volumes of solution and the capacity at breakthrough increase with increasing of contact time, whereas sorbent usage rate decreases. ...

The elimination of finely emulsified oil from waste waters is an important problem, and so far, no satisfactory solution thereto is available worldwide. Here we report some of the results from our studies on the purification of water from different types of oil, to allow waste water re-use in the technological cycle, or use for agricultural irrigation. The isolation of oil is performed by treatment of waste water with polymers of specific adsorption behaviour and solubilizing properties in aqueous medium. Multiblo...

Jurassic brown coal layers of the Kansk-Achinsk basin are the actual source for thermal power stations of West Siberia. The thick (up to 70 m) coal layers lay almost horizontally. Typical unaltered coal is low in trace elements and has, correspondingly, a low radioactivity. However, coal in the uppermost part of the thick dense layers is most often altered to become friable and acquire unusually high contents of some trace elements including natural radioactive ones. Brown coal samples from open-cut mines and natu...

In this paper a total of seven samples (a river sediment, two surface soil samples, and four surrounding rocks) from the Pangaion area, Northern Greece, were collected and analyzed for their content in 10 major (Al, Ca, Cl, Fe, K, Mg, Na, P, S, and Si) and 32 trace elements (Ag, As, B, Ba, Cd, Ce, Co, Cr, Cs, Cu, Ga, Ge, Hg, La, Li, Mn, Mo, Ni, Pb, Rb, Sb, Se, Sn, Sr, Th, Ti, U, V, W, Y, Zn, and Zr). The sampling was based on the major geomorphological processes of the area. The two soil samples are typical of the...

The North-Western Bohemia region takes a unique position in the history of mining in the Czech Republic. Several ore districts are situated here, the welfare of which influenced the development of the Czech state in some periods. Some precious stones mining was also significant. Today the North-Bohemian Basin area is known for its largest Czech brown coal deposit. Whereas ore mining in the region extinguished and the other raw materials mining has relatively small significance, coal mining and the restoration of d...

A comparative study of the content of five macro- and about fifty micro- and trace elements in fly ashes from six coal-burning power plants in Bulgaria is carried out by means of a combination of Chemical Analysis, AAS, X-Ray Luminescence and X-Ray Fluorescence EDA. The elements’ distribution among and within single particles is investigated on the base of the comparison of data from bulk analysis, micro-analysis, and the results from acid leaching tests using 0.1M HNO3. It is established that many heavy metals ...

General environmental problems generated during blast activities in open pit mining are ground vibrations, air pressure, fly rock, dust and poisonous gases and fumes. In some cases, these problems can be the source of some continual disagreements (fear, right and unrighteous complaints, etc.) on inhabitants living close to a blast-based production in a quarry as well as damage on the buildings situated nearby. In this study, the ground vibrations produced by blasting operations performed at a limestone quarry were...

This study analyzes the possibilities of anchorage and reform of a sterile deposition resultant from copper mining activities from around the Brad-Romania mining area. Because this sterile deposition is out of service from about 8 years, the solutions we had to propose according to work of biologic recultivation must stabilized the sterile deposition. After consolidation the danger of rain and snow melting waters will diminish. The main purpose is to avert pollution of area environment factors and concurrently acc...

“The Black Sea Coastal Way Rehabilitation Project” which started seven years ago in order to relief in traffic flow in the Eastern Black Sea Region of Turkey and presently continues to complete their constructions. The project involves the rehabilitation and shortening of the present motorway and hence the construction of new tunnels and riprap material for filling the sea are required in some places. This paper involves one of the blast based tunnel excavations, which is performed for “Yoroz Tunnel” situa...

A hydrochemical study is conducted in the Faria basin / NE of the West Bank to define water types and to determine hydrochemical parameters of the aquifer system. More than 150 water samples were analysed, which covered all springs and wells. The physical and chemical properties were determined. The major cations Ca2+, Mg2+, Na+ and K+ and the major anions HCO3-, Cl-, SO42- and NO3- were analysed. The minor constituents of SiO2, F-, Br- and PO43- and the trace elements Cu, Cd, Fe, Mn, Cr, Zn and Pb were determined...

This paper presents investigation of the environmental effects of ground vibration and air blast induced by blasting in various quarries located at Turkish Republic of Northern Cyprus. Within the scope of this study, scaled distance components have been recorded for two shots at the BeЕџparmak Company, two shots at the G\"urdaДџ Company, one shot at the Levent Mosaic Company and one shot at the ArpalД±klД± Company, totally 6 shots at different times. And also, ground vibrations and air blasts produced by these sho...

A bottom ash and a fly ash sample from Unit 1 of the Agios Dimitrios Power Plant, Northern Greece, were subjected to a one stage leaching procedure (Synthetic Groundwater Leaching Procedure – SGLP). The lignite burned in it derives from the Southern Field Mine from the Lignite Centre of Western Macedonia. The Relative Mass Leached (RML) for ten major (Al, P, Ca, Mg, K, Fe, Na, Si, S and Ti) and forty eight trace elements (Li, Be, B, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Zr, Nb, Mo, Ag, Cd, Sn, Sb...

This paper presents the results from the study of heavy metals contamination of paddy soil of the Ko\vcani Field (Eastern Macedonia), an area with extensive agricultural production. The soil of the Ko\vcani Field is supposed to be polluted by heavy metals due to mining activities and acid mine drainage from Zletovo-Kratovo and Sasa-Toranica ore districts. This was supposed by the fact that acid mine drainage and direct input of Zletovo Pb-Zn mine effluents of pH 3.4 with mean Pb concentrations of 66 mg l-1, Zn at ...

The problems for the protection of the environment from various pollutants are considered worldwide as fundamental for mankind. A large number of people are nowadays exposed to the different pollutions in waste and potable water. The pollutions have a harmful effect on the biological system. Some regions in Bulgaria and Turkey have serious problems with water contaminated with metal ions. The heavy metals (Hg, As, Cd, Mn, etc.) have a harmful effect on human physiology and other biological system when they are fou...

The North-Bohemian Basin area is known for its largest Czech brown coal deposit. About 50\% brown coal reserves have been exploited in the North-Bohemian Basin by the mining company of Severoceske doly, a.s. (North Bohemian Mines) today. The opencast mining of brown coal naturally led to vast landscape damages. Therefore reclamation work has acquired great significance. The specific feature of Severoceske doly, a.s. mining is the fact that the mining has been realized in two geologically absolutely different local...

The investigations made by us about the micromorphology of the foliar surfaces of two species of gymnosperms in the industrial areas Bicaz and TaЕџca (the NeamЕЈ District, Romania). The investigations of electronic microscopy (S.E.M.) made up at the level of necrotic and/or chlorosis surfaces (top, middle, basis) of the acicular leaves of Pinus sylvestris and Pinus nigra showed changes of the cuticular surface, their contortion, caused by the total disappearance of the parallelism between the cuticular prints, the...

Bulgaria occupies a unique position in south-east Europe in terms of river basin management and control because contamination from metal extraction and processing industries not only has a potential significant trans-border impact but also affects both the Mediterranean and Black Seas. However, to date, no whole basin source to sink study of metal contamination has yet been conducted in the country. This paper begins to address this issue by presenting preliminary results from a survey conducted in August 2004 of ...

In this paper we present the critical situation of four species of Gymnosperms (Pinus nigra and Pinus sylvestris, Picea abies, Abies alba.) which can be found in areas of industrial zone from Bicaz District, Romania. The pollutants are mainly solid: lime and cement dust. Our investigation it is about the physiological and histo – anatomical modifications of the leaves (needles). We want to stress the fact that the large quantity of dry substance from the leaves isn’t always related to the distance from the pol...

During 2004, pluridisciplinary investigations have been devoted to the abiotic and biotic characteristics of the anthropized ecosystem developed in relation with the domestic litter hills at Tomesti, Iasi. Both abiotic (climate, soil, air) and biotic (talobyontes, chormobyontes, phytophagous invertebrata) parameters have been recorded. The results showed that the urban wastes deposit has a complex impact upon the environment: air pollution with odours and dust, soil pollution with heavy metals (Pb, Ni, Cr, Cd, Cu)...

This study is about the investigation of socio-economic factors in order to enhance preservation of prominent Basin and Lake Regions. The ongoing joint research and development project in Kucukcekmece Basin, Istanbul, aims to implement an environmental master plan for the region and to establish a coordination department which includes coordination of municipality, government institutions and NGOs each other. In addition, monitoring of the water resources within the basin is an important point of the project. Kucu...

This paper focuses on the potential environmental benefits afforded by use of paste backfill technology when tailings are sulfide-bearing and provides a case study chosen from an underground mine in north-east Turkey in order to illustrate these benefits. Additionally, it includes discussions on different slump values with varying cement contents under 28-day uniaxial compressive strength tests for mine tailings and determines the rheological properties of mine tailings with respect to paste production.

Experimental modeling with the aim of elucidation of the geochemical behaviour of heavy metal pollutants (Pb, Zn, Cd, Cu, Ni, Mn, Fe) and As during interphase processes in metallurgy contaminated area are carried out in 3 aspects: I. Water-soil interaction chemical simulation: 3D –lixiviation of soils and acid rain impact modeling, revealing consequences for a secondary remobilization and increasing the environmental risk for groundwater, vegetables, etc. II. Sorption ability of soils with fixing possibilities, ...